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Published February 15, 2017 | Supplemental Material + Accepted Version
Journal Article Open

A Fischer Indolization Strategy toward the Total Synthesis of (–)-Goniomitine


A Fischer indolization strategy toward the core of (–)-goniomitine is reported. Initial investigations into the Pd-catalyzed asymmetric allylic alkylation of dihydropyrido[1,2-a]indolone (DHPI) substrates are also discussed.

Additional Information

© 2017 The Japan Institute of Heterocyclic Chemistry. Published online: 15th February, 2017. The authors wish to thank NIH-NIGMS (R01GM080269), Amgen, the Gordon and Betty Moore Foundation, and Caltech for financial support. B.P.P. thanks the NSF for a predoctoral fellowship (Grant DGE-1144469). Y. N. thanks Toray Industries Inc. for a postdoctoral fellowship. The authors thank Dr. Scott Virgil (Caltech) and the Caltech Center for Catalysis and Chemical Synthesis, for instrumentation assistance. Katerina Korch is acknowledged for experimental assistance.

Attached Files

Accepted Version - nihms876040.pdf

Supplemental Material - COM-16-S_S_80_SI.pdf


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