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Published January 20, 2005 | Supplemental Material
Journal Article Open

Chemoselective Construction of Substituted Conjugated Dienes Using an Olefin Cross-Metathesis Protocol


Various substituted conjugated dienes have been made by olefin cross-metathesis. Using either electronic or steric "protection," one of the olefins of the conjugated diene was deactivated relative to the other for cross-metathesis. The reactions proceed with very high chemoselectivity and, when steric deactivation is used, very high diastereoselectivity.

Additional Information

© 2005 American Chemical Society. Received 7 October 2004. Published online 22 December 2004. Published in print 1 January 2005. This work was supported by a research grant from the National Institutes of Health.

Attached Files

Supplemental Material - ol047929zsi20041007_115810.pdf

Supplemental Material - ol047929zsi20041012_052027.pdf


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