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Number of items: 281.

2021

Han, Seo-Jung and Cavitt, Marchello A. and Stoltz, Brian M. (2021) A Synthetic Strategy toward Eight-Membered Cyclic Amines by Cycloetherification and Claisen Rearrangement. Organic Letters, 23 (9). pp. 3300-3303. ISSN 1523-7060. doi:10.1021/acs.orglett.1c00763. https://resolver.caltech.edu/CaltechAUTHORS:20210416-080746750

Yu, Donna D. and Van Citters, Gregg and Li, Hongzhi et al. (2021) Discovery of Novel Modulators for the PPARα (Peroxisome Proliferator Activated Receptor α): Potential Therapies for Nonalcoholic Fatty Liver Disease. Bioorganic and Medicinal Chemistry . ISSN 0968-0896. doi:10.1016/j.bmc.2021.116193. (In Press) https://resolver.caltech.edu/CaltechAUTHORS:20210507-140316316

Süsse, Lars and Stoltz, Brian M. (2021) Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts. Chemical Reviews, 121 (7). pp. 4084-4099. ISSN 0009-2665. doi:10.1021/acs.chemrev.0c01115. https://resolver.caltech.edu/CaltechAUTHORS:20210212-132145336

Zhang, Gang and Li, Shan and Wang, Feng et al. (2021) A covalent p97/VCP ATPase inhibitor can overcome resistance to CB-5083 and NMS-873 in colorectal cancer cells. European Journal of Medicinal Chemistry, 213 . Art. No. 113148. ISSN 0223-5234. https://resolver.caltech.edu/CaltechAUTHORS:20210104-164231600

2020

Fulton, Tyler J. and Cusumano, Alexander Q. and Alexy, Eric J. et al. (2020) Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids. Journal of the American Chemical Society, 142 (52). pp. 21938-21947. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20201104-135041447

Kim, Kelly E. and Sakazaki, Yuka and Stoltz, Brian M. (2020) Synthesis of non-natural cyanthiwigin–gagunin hybrids through late-stage diversification of the cyanthiwigin natural product core. Tetrahedron, 76 (51). Art. No. 130755. ISSN 0040-4020. https://resolver.caltech.edu/CaltechAUTHORS:20191105-093732898

Kim, Alexia N. and Stoltz, Brian M. (2020) Recent Advances in Homogeneous Catalysts for the Asymmetric Hydrogenation of Heteroarenes. ACS Catalysis, 10 (23). pp. 13834-13851. ISSN 2155-5435. https://resolver.caltech.edu/CaltechAUTHORS:20201112-103611899

Cusumano, Alexander Q. and Goddard, William A., III and Stoltz, Brian M. (2020) Transition Metal Catalyzed [π2s + π2s + σ2s + σ2s] Pericyclic Reaction: Woodward–Hoffmann Rules, Aromaticity, and Electron Flow. Journal of the American Chemical Society, 142 (45). pp. 19033-19039. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20201028-103039420

Ngamnithiporn, Aurapat and Iwayama, Toshihiko and Bartberger, Michael D. et al. (2020) Enantioselective synthesis of highly oxygenated acyclic quaternary center-containing building blocks via palladium-catalyzed decarboxylative allylic alkylation of cyclic siloxyketones. Chemical Science, 11 (40). pp. 11068-11071. ISSN 2041-6520. https://resolver.caltech.edu/CaltechAUTHORS:20200925-104734427

Fulton, Tyler J. and Chen, Anthony Y. and Bartberger, Michael D. et al. (2020) Enantioselective Total Synthesis of (–)-Myrifabral A and B. Chemical Science, 11 (39). pp. 10802-10806. ISSN 2041-6520. https://resolver.caltech.edu/CaltechAUTHORS:20200304-153439734

Kenseth, Christopher M. and Hafeman, Nicholas J. and Huang, Yuanlong et al. (2020) Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol. Environmental Science and Technology, 54 (20). pp. 12829-12839. ISSN 0013-936X. https://resolver.caltech.edu/CaltechAUTHORS:20200819-162804852

Wolf, William J. and Li, Jiaming and Jones, Simon C. et al. (2020) Efficient Synthesis of Geminal-Dialkyl Dienes for Olefin Metathesis Polymerization. Macromolecules, 53 (18). pp. 7803-7809. ISSN 0024-9297. https://resolver.caltech.edu/CaltechAUTHORS:20200911-133138265

Cusumano, Alexander Q. and Stoltz, Brian M. and Goddard, William A., III (2020) Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp³)–C(sp³) Cross-Coupling. Journal of the American Chemical Society, 142 (32). pp. 13917-13933. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20200710-102850852

Kenseth, Christopher M. and Hafeman, Nicholas J. and Huang, Yuanlong et al. (2020) Synthesis of carboxylic acid and dimer ester surrogates to constrain the abundance and distribution of molecular products in α-pinene and β-pinene secondary organic aerosol. In: 260th ACS National Meeting & Exposition, 23-27 August 2020, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20201221-084129753

Inanaga, Kazato and Wollenburg, Marco and Bachman, Shoshana et al. (2020) Catalytic enantioselective synthesis of carbocyclic and heterocyclic spiranes via a decarboxylative aldol cyclization. Chemical Science, 11 (28). pp. 7390-7395. ISSN 2041-6520. PMCID PMC7574022. https://resolver.caltech.edu/CaltechAUTHORS:20200702-103837298

Duquette, Douglas C. and Cusumano, Alexander Q. and Lefoulon, Louise et al. (2020) Probing Trends in Enantioinduction via Substrate Design: Palladium-Catalyzed Decarboxylative Allylic Alkylation of α-Enaminones. Organic Letters, 22 (13). pp. 4966-4969. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20200622-104137176

Lavernhe, Rémi and Alexy, Eric J. and Zhang, Haiming et al. (2020) Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α-N-Pyrrolyl/Indolyl Ketones. Organic Letters, 22 (11). pp. 4272-4275. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20200519-093555551

Baek, Doohyun and Ryu, Huijeong and Ryu, Ji Yeon et al. (2020) Catalytic enantioselective synthesis of tetrasubstituted chromanones via palladium-catalyzed asymmetric conjugate arylation using chiral pyridine-dihydroisoquinoline ligands. Chemical Science, 11 (18). pp. 4602-4607. ISSN 2041-6520. PMCID PMC7574023. https://resolver.caltech.edu/CaltechAUTHORS:20200420-124420412

Hafeman, Nicholas J. and Loskot, Steven A. and Reimann, Christopher E. et al. (2020) The Total Synthesis of (–)-Scabrolide A. Journal of the American Chemical Society, 142 (19). pp. 8585-8590. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20200304-101308383

Kim, Alexia N. and Ngamnithiporn, Aurapat and Welin, Eric R. et al. (2020) Iridium-Catalyzed Enantioselective and Diastereoselective Hydrogenation of 1,3-Disubstituted Isoquinolines. ACS Catalysis, 10 (5). pp. 3241-3248. ISSN 2155-5435. https://resolver.caltech.edu/CaltechAUTHORS:20200211-083029861

Jette, Carina I. and Tong, Z. Jaron and Hadt, Ryan G. et al. (2020) Copper-Catalyzed Enantioselective Allylic Alkylation with a γ-Butyrolactone-Derived Silyl Ketene Acetal. Angewandte Chemie International Edition, 59 (5). pp. 2033-2038. ISSN 1433-7851. PMCID PMC7051182 . https://resolver.caltech.edu/CaltechAUTHORS:20191120-075819004

Lavernhe, Rémi and Alexy, Eric J. and Zhang, Haiming et al. (2020) Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Protected Benzoin-Derived Enol Carbonates. Advanced Synthesis and Catalysis, 362 (2). pp. 344-347. ISSN 1615-4150. PMCID PMC7942817. https://resolver.caltech.edu/CaltechAUTHORS:20191106-101057290

Park, Dongseong and Jette, Carina I. and Kim, Jiyun et al. (2020) Enantioselective Alkynylation of Trifluoromethyl Ketones Catalyzed by Cation-Binding Salen Nickel Complexes. Angewandte Chemie International Edition, 59 (2). pp. 775-779. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20191112-095230680

2019

Li, Jiaming and Stoltz, Brian M. and Grubbs, Robert H. (2019) Enantioselective Synthesis of 15-Deoxy-Δ¹²,¹⁴-Prostaglandin J₂. Organic Letters, 21 (24). pp. 10139-10142. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20191209-080257479

Wright, Austin C. and Stoltz, Brian M. (2019) Enantioselective construction of the tricyclic core of curcusones A–D via a cross-electrophile coupling approach. Chemical Science, 10 (45). pp. 10562-10565. ISSN 2041-6520. PMCID PMC6988747. https://resolver.caltech.edu/CaltechAUTHORS:20191008-075046379

Wright, Austin C. and Lee, Chung Whan and Stoltz, Brian M. (2019) Progress toward the Enantioselective Synthesis of Curcusones A–D via a Divinylcyclopropane Rearrangement Strategy. Organic Letters, 21 (23). pp. 9658-9662. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20191125-151328722

Sercel, Zachary P. and Sun, Alexander W. and Stoltz, Brian M. (2019) Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of 1,4-Diazepan-5-ones. Organic Letters, 21 (22). pp. 9158-9161. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20191031-141639871

Velasco-Rubio, Álvaro and Alexy, Eric J. and Yoritate, Makoto et al. (2019) Stereospecific Overman Rearrangement of Substituted Cyclic Vinyl Bromides: Access to Fully Substituted α-Amino Ketones. Organic Letters, 21 (22). pp. 8962-8965. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20191030-100426727

Schuman, David P. and Liu, Wen‐Bo and Nesnas, Nasri et al. (2019) Transition‐Metal‐Free Catalytic C─H Bond Silylation. In: Organosilicon Chemistry: Novel Approaches and Reactions. Wiley , pp. 213-240. ISBN 9783527344536. https://resolver.caltech.edu/CaltechAUTHORS:20191111-083817296

Sun, Alexander W. and Lackner, Sebastian and Stoltz, Brian M. (2019) Modularity: Adding New Dimensions to Total Synthesis. Trends in Chemistry, 1 (7). pp. 630-643. ISSN 2589-5974. https://resolver.caltech.edu/CaltechAUTHORS:20190624-132958661

Jones, Christopher G. and Asay, Matthew and Kim, Lee Joon et al. (2019) Characterization of Reactive Organometallic Species via MicroED. ACS Central Science, 5 (9). pp. 1507-1513. ISSN 2374-7943. PMCID PMC6764211. https://resolver.caltech.edu/CaltechAUTHORS:20190906-134149357

Sun, Alexander W. and Bulterys, Philip L. and Bartberger, Michael D. et al. (2019) Incorporation of a chiral gem-disubstituted nitrogen heterocycle yields an oxazolidinone antibiotic with reduced mitochondrial toxicity. Bioorganic and Medicinal Chemistry Letters, 29 (18). pp. 2686-2689. ISSN 0960-894X. PMCID PMC6711789 . https://resolver.caltech.edu/CaltechAUTHORS:20190718-083115245

Wright, Austin C. and Du, Yun Emily and Stoltz, Brian M. (2019) A Small-scale Procedure for Acid-catalyzed Ketal Formation. Journal of Organic Chemistry, 84 (17). pp. 11258-11260. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20190812-105551569

Fulton, Tyler J. and Wu, Brenda and Alexy, Eric J. et al. (2019) Palladium-catalyzed α,β-dehydrogenation of acyclic ester equivalents promoted by a novel electron deficient phosphinooxazoline ligand. Tetrahedron, 75 (31). pp. 4104-4109. ISSN 0040-4020. PMCID PMC7119178. https://resolver.caltech.edu/CaltechAUTHORS:20190603-092206331

Alexy, Eric J. and Fulton, Tyler J. and Zhang, Haiming et al. (2019) Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates. Chemical Science, 10 (23). pp. 5996-6000. ISSN 2041-6520. PMCID PMC6566452. https://resolver.caltech.edu/CaltechAUTHORS:20190517-104313815

Craig, Robert A., II and Smith, Russell C. and Roizen, Jennifer L. et al. (2019) Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Synthesis of a Series of Ineleganoloids by Oxidation State Manipulation of the Carbocyclic Core. Journal of Organic Chemistry, 84 (12). pp. 7722-7746. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20190508-090511086

Harned, Andrew M. and Stoltz, Brian M. (2019) Development of a catalytic enantioselective synthesis of the guanacastepene and heptemerone tricyclic core. Tetrahedron, 75 (24). pp. 3166-3177. ISSN 0040-4020. PMCID PMC6959853. https://resolver.caltech.edu/CaltechAUTHORS:20190227-085618755

Lee, Chung Whan and Taylor, Buck L. H. and Petrova, Galina P. et al. (2019) An unexpected Ireland–Claisen rearrangement cascade during the synthesis of the tricyclic core of Curcusone C: Mechanistic elucidation by trial-and-error and automatic artificial force-induced reaction (AFIR) computations. Journal of the American Chemical Society, 141 (17). pp. 6995-7004. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20190325-131628168

Wright, Austin C. and Stoltz, Brian M. (2019) Discussion Addendum for: The Direct Acyl-Alkylation of Arynes. Preparation of Methyl 2-(2-acetylphenyl)acetate. Organic Syntheses, 96 . pp. 80-97. ISSN 2333-3553. https://resolver.caltech.edu/CaltechAUTHORS:20190903-160057854

Yamano, Michael M. and Knapp, Rachel R. and Ngamnithiporn, Aurapat et al. (2019) Cycloadditions of Oxacyclic Allenes and a Catalytic Asymmetric Entryway to Enantioenriched Cyclic Allenes. Angewandte Chemie International Edition, 58 (17). pp. 5653-5657. ISSN 1433-7851. PMCID PMC6456397. https://resolver.caltech.edu/CaltechAUTHORS:20190227-131909461

Sun, Alexander W. and Stoltz, Brian M. (2019) Discussion Addendum for: Preparation of (S)-tert-ButylPHOX and (S)-2-Allyl-2-Methylcyclohexanone. In: Organic Syntheses. John Wiley & Sons , Hoboken, NJ. ISBN 9780471264224. https://resolver.caltech.edu/CaltechAUTHORS:20190404-143251363

Sun, Alexander and Stoltz, Brian Mark (2019) Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation. In: 257th ACS National Meeting & Exposition, 31 March - 4 April 2019, Orlando, FL. https://resolver.caltech.edu/CaltechAUTHORS:20190325-092717158

Jette, Carina I. and Geibel, Irina and Bachman, Shoshana et al. (2019) Palladium-Catalyzed Construction of Quaternary Stereocenters by Enantioselective Arylation of γ-Lactams with Aryl Chlorides and Bromides. Angewandte Chemie International Edition, 58 (13). pp. 4297-4301. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20190124-110425627

Han, Seo-Jung and Bhat, Vikram and Stoltz, Brian M. et al. (2019) Atroposelective Synthesis of PINAP via Dynamic Kinetic Asymmetric Transformation. Advanced Synthesis and Catalysis, 361 (3). pp. 441-444. ISSN 1615-4150. https://resolver.caltech.edu/CaltechAUTHORS:20181113-112609134

Sun, Alexander W. and Hess, Stephan N. and Stoltz, Brian M. (2019) Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation. Chemical Science, 10 (3). pp. 788-792. ISSN 2041-6520. PMCID PMC6345351. https://resolver.caltech.edu/CaltechAUTHORS:20181106-111914131

Welin, Eric R. and Ngamnithiporn, Aurapat and Klatte, Max et al. (2019) Concise total syntheses of (–)-jorunnamycin A and (–)-jorumycin enabled by asymmetric catalysis. Science, 363 (6424). pp. 270-275. ISSN 0036-8075. PMCID PMC7017906. https://resolver.caltech.edu/CaltechAUTHORS:20181221-091725806

Praske, Eric and Otkjær, Rasmus V. and Crounse, John D. et al. (2019) Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals. Journal of Physical Chemistry A, 123 (2). pp. 590-600. ISSN 1089-5639. https://resolver.caltech.edu/CaltechAUTHORS:20181217-080428895

Li, Jiaming and Ahmed, Tonia S. and Xu, Chen et al. (2019) Concise Syntheses of Δ^(12)-Prostaglandin J Natural Products via Stereoretentive Metathesis. Journal of the American Chemical Society, 141 (1). pp. 154-158. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20181212-100802379

2018

Shockley, Samantha E. and Hethcox, J. Caleb and Stoltz, Brian M. (2018) Intermolecular Stereoselective Iridium-Catalyzed Allylic Alkylation: An Evolutionary Account. Synlett, 29 (19). pp. 2481-2492. ISSN 0936-5214. PMCID PMC6870865. https://resolver.caltech.edu/CaltechAUTHORS:20181205-140604109

Jones, Christopher G. and Martynowycz, Michael W. and Hattne, Johan et al. (2018) The CryoEM Method MicroED as a Powerful Tool for Small Molecule Structure Determination. ACS Central Science, 4 (11). pp. 1587-1592. ISSN 2374-7943. PMCID PMC6276044. https://resolver.caltech.edu/CaltechAUTHORS:20181101-140146236

Davies, Huw M. L. and Itami, Kenichiro and Stoltz, Brian M. (2018) New directions in natural product synthesis. Chemical Society Reviews, 47 (21). pp. 7828-7829. ISSN 0306-0012. https://resolver.caltech.edu/CaltechAUTHORS:20181029-094838158

Liu, Wenbin and Ren, Zhi and Bosse, Aaron T. et al. (2018) Catalyst-Controlled Selective Functionalization of Unactivated C–H Bonds in the Presence of Electronically Activated C–H Bonds. Journal of the American Chemical Society, 140 (38). pp. 12247-12255. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20180917-125103681

Lu, Yanhui and Goldstein, Elizabeth L. and Stoltz, Brian M. (2018) Palladium-Catalyzed Enantioselective C_(sp)^3–C_(sp)^3 Cross-Coupling for the Synthesis of (Poly)fluorinated Chiral Building Blocks. Organic Letters, 20 (18). pp. 5657-5660. ISSN 1523-7060. PMCID PMC6192028. https://resolver.caltech.edu/CaltechAUTHORS:20180905-091810349

Wang, Xin and Zhu, Ming-Hui and Schuman, David P. et al. (2018) General and Practical Potassium Methoxide/Disilane-Mediated Dehalogenative Deuteration of (Hetero)Arylhalides. Journal of the American Chemical Society, 140 (35). pp. 10970-10974. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20180806-125449354

Alexy, Eric J. and Zhang, Haiming and Stoltz, Brian M. (2018) Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates. Journal of the American Chemical Society, 140 (32). pp. 10109-10112. ISSN 0002-7863. PMCID PMC6103296. https://resolver.caltech.edu/CaltechAUTHORS:20180727-091530074

Kenseth, Christopher M. and Huang, Yuanlong and Zhao, Ran et al. (2018) Synergistic O_3 + OH oxidation pathway to extremely low-volatility dimers revealed in β-pinene secondary organic aerosol. Proceedings of the National Academy of Sciences of the United States of America, 115 (33). pp. 8301-8306. ISSN 0027-8424. PMCID PMC6099901. https://resolver.caltech.edu/CaltechAUTHORS:20180803-132305205

Al Saihati, Zainab and Haibach, Michael C. and Swisher, Nicholas A. et al. (2018) Cyclic alkanes transfer dehydrogenation using homogeneous iridium pincer catalysts. In: 256th American Chemical Society National Meeting & Exposition, 19-23 August 2018, Boston, MA. https://resolver.caltech.edu/CaltechAUTHORS:20181108-143733231

Defieber, Christian and Mohr, Justin T. and Grabovyl, Gennadii A. et al. (2018) Short Enantioselective Formal Synthesis of (–)-Platencin. Synthesis-Stuttgart, 50 (22). pp. 4359-4368. ISSN 0039-7881. PMCID PMC6498846. https://resolver.caltech.edu/CaltechAUTHORS:20180730-120150815

Hartrampf, Nina and Winter, Nils and Pupo, Gabriele et al. (2018) Total Synthesis of the Norhasubanan Alkaloid Stephadiamine. Journal of the American Chemical Society, 140 (28). pp. 8675-8680. ISSN 0002-7863. PMCID PMC6130314. https://resolver.caltech.edu/CaltechAUTHORS:20180611-142236882

Hethcox, J. Caleb and Shockley, Samantha E. and Stoltz, Brian M. (2018) Enantioselective Synthesis of Vicinal All-Carbon Quaternary Centers via Iridium-Catalyzed Allylic Alkylation. Angewandte Chemie International Edition, 57 (28). pp. 8664-8667. ISSN 1433-7851. PMCID PMC6033654. https://resolver.caltech.edu/CaltechAUTHORS:20180514-112203501

Krout, Michael R. and Henry, Christopher E. and Jensen, Thomas et al. (2018) Wolff/Cope Approach to the AB Ring of the Sesterterpenoid Variecolin. Journal of Organic Chemistry, 83 (13). pp. 6995-7009. ISSN 0022-3263. PMCID PMC6035096. https://resolver.caltech.edu/CaltechAUTHORS:20180104-140230299

Pritchett, Beau P. and Stoltz, Brian M. (2018) Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids. Natural Product Reports, 35 (6). pp. 559-574. ISSN 0265-0568. PMCID PMC6013405. https://resolver.caltech.edu/CaltechAUTHORS:20180416-135313177

Craig, Robert A., II and Smith, Russell C. and Roizen, Jennifer L. et al. (2018) Development of a Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Asymmetric Formation of the Polycyclic Norditerpenoid Carbocyclic Core by Tandem Annulation Cascade. Journal of Organic Chemistry, 83 (7). pp. 3467-3485. ISSN 0022-3263. PMCID PMC5889334. https://resolver.caltech.edu/CaltechAUTHORS:20180327-133635374

Kim, Kelly E. and Adams, Ashley M. and Chiappini, Nicholas D. et al. (2018) The Cyanthiwigin Natural Product Core as a Complex Molecular Scaffold for Comparative Late-Stage C–H Functionalization Studies. Journal of Organic Chemistry, 83 (6). pp. 3023-3033. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20180109-144403638

Ngamnithiporn, Aurapat and Jette, Carina I. and Bachman, Shoshana et al. (2018) Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols. Chemical Science, 2018 (9). pp. 2547-2551. ISSN 2041-6520. PMCID PMC5912103. https://resolver.caltech.edu/CaltechAUTHORS:20180207-083556564

Stoltz, Brian (2018) Award Address (ACS Award for Creative Work in Synthetic Organic Chemistry sponsored by MilliporeSigma). Complex natural products as a driving force for discovery in organic chemistry. In: 255th American Chemical Society National Meeting & Exposition, March 18-22, 2018, New Orleans, LA. https://resolver.caltech.edu/CaltechAUTHORS:20180413-085522795

Leung, Joyce and Bederman, Aaron and Njardarson, Jon et al. (2018) Total synthesis of (±)-phomoidride D: A 22 year odyssey. In: 255th American Chemical Society National Meeting & Exposition, March 18-22, 2018, New Orleans, LA. https://resolver.caltech.edu/CaltechAUTHORS:20180712-081511897

Leung, Joyce C. and Bedermann, Aaron A. and Njardarson, Jón T. et al. (2018) Total Synthesis of (±)-Phomoidride D. Angewandte Chemie International Edition, 57 (7). pp. 1991-1994. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20200415-101219737

Duquette, Douglas Charles and Jensen, Thomas and Stoltz, Brian Mark (2018) Progress towards the total synthesis of hamigerans C and D: a direct approach to an elaborated 6-7-5 carbocyclic core. Journal of Antibiotics, 71 (2). pp. 263-267. ISSN 0021-8820. PMCID PMC5788718. https://resolver.caltech.edu/CaltechAUTHORS:20170906-153516673

Chen, Anthony Y. and Lu, Qianqian and Fu, Yao et al. (2018) Isocanthine Synthesis via Rh(III)-Catalyzed Intramolecular C-H Functionalization. Journal of Organic Chemistry, 83 (1). pp. 330-337. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20171129-075958117

Praske, Eric and Otkjær, Rasmus V. and Crounse, John D. et al. (2018) Atmospheric autoxidation is increasingly important in urban and suburban North America. Proceedings of the National Academy of Sciences of the United States of America, 115 (1). pp. 64-69. ISSN 0027-8424. PMCID PMC5776813. https://resolver.caltech.edu/CaltechAUTHORS:20171219-073339592

2017

Roizen, Jennifer L. and Jones, Amanda C. and Smith, Russell C. et al. (2017) Model Studies to Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps. Journal of Organic Chemistry, 82 (24). pp. 13051-13067. ISSN 0022-3263. PMCID PMC5732049. https://resolver.caltech.edu/CaltechAUTHORS:20171107-103337734

Haibach, Michael C. and Stoltz, Brian M. and Grubbs, Robert H. (2017) Catalytic Reduction of Alkyl and Aryl Bromides Using Propan-2-ol. Angewandte Chemie International Edition, 56 (47). pp. 15123-15126. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20171004-144313124

Alexy, Eric J. and Virgil, Scott C. and Bartberger, Michael D. et al. (2017) Enantioselective Pd-Catalyzed Decarboxylative Allylic Alkylation of Thiopyranones. Access to Acyclic, Stereogenic α-Quaternary Ketones. Organic Letters, 19 (19). pp. 5007-5009. ISSN 1523-7060. PMCID PMC5632216. https://resolver.caltech.edu/CaltechAUTHORS:20170914-131404458

Liniger, Marc and Liu, Yiyang and Stoltz, Brian M. (2017) Sequential Ruthenium Catalysis for Olefin Isomerization and Oxidation: Application to the Synthesis of Unusual Amino Acids. Journal of the American Chemical Society, 139 (39). pp. 13944-13949. ISSN 0002-7863. PMCID PMC5628162. https://resolver.caltech.edu/CaltechAUTHORS:20170918-101644915

Pritchett, Beau P. and Donckele, Etienne J. and Stoltz, Brian M. (2017) Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A. Angewandte Chemie International Edition, 56 (41). pp. 12624-12627. ISSN 1433-7851. PMCID PMC5896324. https://resolver.caltech.edu/CaltechAUTHORS:20170905-134054944

Shockley, Samantha E. and Hethcox, J. Caleb and Stoltz, Brian M. (2017) Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation. Angewandte Chemie International Edition, 56 (38). pp. 11545-11548. ISSN 1433-7851. PMCID PMC5674796. https://resolver.caltech.edu/CaltechAUTHORS:20170719-091950600

Shockley, Samantha E. and Hethcox, J. Caleb and Stoltz, Brian M. (2017) Asymmetric Synthesis of All-Carbon Quaternary Spirocycles via a Catalytic Enantioselective Allylic Alkylation Strategy. Tetrahedron Letters, 58 (34). pp. 3341-3343. ISSN 0040-4039. PMCID PMC5578629. https://resolver.caltech.edu/CaltechAUTHORS:20170707-100417876

Loskot, Steven A. and Romney, David K. and Arnold, Frances H. et al. (2017) Enantioselective Total Synthesis of Nigelladine A via Late-Stage C–H Oxidation Enabled by an Engineered P450 Enzyme. Journal of the American Chemical Society, 139 (30). pp. 10196-10199. ISSN 0002-7863. PMCID PMC5679227. https://resolver.caltech.edu/CaltechAUTHORS:20170720-100846797

Shockley, Samantha and Hethcox, Caleb and Stoltz, Brian (2017) Recent developments in stereoselective iridium-catalyzed allylic alkylation methodologies. In: 254th American Chemical Society National Meeting & Exposition, August 20-24, 2017, Washington, DC. https://resolver.caltech.edu/CaltechAUTHORS:20170913-084235803

Stoltz, Brian M. (2017) Twists and turns of lactam research. In: 254th American Chemical Society National Meeting & Exposition, August 20-24, 2017, Washington, DC. https://resolver.caltech.edu/CaltechAUTHORS:20170919-130910278

Starkov, Pavel and Moore, Jared T. and Duquette, Douglas C. et al. (2017) Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully-Substituted Amide Enolates. Journal of the American Chemical Society, 139 (28). pp. 9615-9620. ISSN 0002-7863. PMCID PMC5555155. https://resolver.caltech.edu/CaltechAUTHORS:20170623-095559709

Craig, Robert A., II and Stoltz, Brian M. (2017) Polycyclic Furanobutenolide-Derived Cembranoid and Norcembranoid Natural Products: Biosynthetic Connections and Synthetic Efforts. Chemical Reviews, 117 (12). pp. 7878-7909. ISSN 0009-2665. PMCID PMC5497599. https://resolver.caltech.edu/CaltechAUTHORS:20170519-105858158

Banerjee, Shibdas and Yang, Yun-Fang and Jenkins, Ian D. et al. (2017) Ionic and Neutral Mechanisms for C–H Bond Silylation of Aromatic Heterocycles Catalyzed by Potassium t-Butoxide. Journal of the American Chemical Society, 139 (20). pp. 6880-6887. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170502-104649589

Liu, Wen-Bo and Schuman, David P. and Yang, Yun-Fang et al. (2017) Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study. Journal of the American Chemical Society, 139 (20). pp. 6867-6879. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170413-121146154

Hethcox, J. Caleb and Shockley, Samantha E. and Stoltz, Brian M. (2017) Enantioselective Iridium-Catalyzed Allylic Alkylation Reactions of Masked Acyl Cyanide Equivalents. Organic Letters, 19 (7). pp. 1527-1529. ISSN 1523-7060. PMCID PMC5470644. https://resolver.caltech.edu/CaltechAUTHORS:20170316-160746005

Stoltz, Brian M. (2017) Complex natural products as a driving force for discovery in organic chemistry. In: 253rd American Chemical Society National Meeting & Exposition, April 2-6, 2017, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20170503-152924409

Bhat, Vikram and Welin, Eric R. and Guo, Xuelei et al. (2017) Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations. Chemical Reviews, 117 (5). pp. 4528-4561. ISSN 0009-2665. PMCID PMC5516946. https://resolver.caltech.edu/CaltechAUTHORS:20170211-113501417

Klare, Hendrik F. T. and Goldberg, Alexander F. G. and Duquette, Douglas C. et al. (2017) Oxidative Fragmentations and Skeletal Rearrangements of Oxindole Derivatives. Organic Letters, 19 (5). pp. 988-991. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20170216-101807646

Pritchett, Beau P. and Kikuchi, Jun and Numajiri, Yoshitaka et al. (2017) A Fischer Indolization Strategy toward the Total Synthesis of (–)-Goniomitine. Heterocycles, 95 (2). pp. 1245-1253. ISSN 0385-5414. PMCID PMC5502790. https://resolver.caltech.edu/CaltechAUTHORS:20170706-132827697

Toutov, Anton A. and Betz, Kerry N. and Schuman, David P. et al. (2017) Alkali metal hydroxide–catalyzed C(sp)–H bond silylation. Journal of the American Chemical Society, 139 (4). pp. 1668-1674. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170104-153320118

Craig, Robert A., II and Roizen, Jennifer L. and Smith, Russell C. et al. (2017) Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade. Chemical Science, 8 (1). pp. 507-514. ISSN 2041-6520. PMCID PMC5321630; PMC6349058. https://resolver.caltech.edu/CaltechAUTHORS:20160908-102036330

2016

Hethcox, J. Caleb and Shockley, Samantha E. and Stoltz, Brian M. (2016) Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride. Angewandte Chemie International Edition, 55 (52). pp. 16092-16095. ISSN 1433-7851. PMCID PMC5207348. https://resolver.caltech.edu/CaltechAUTHORS:20161205-102308894

Pushkarskaya, Eugenia and Wong, Brian and Han, Chong et al. (2016) Single-step synthesis of 3-hydroxycarbazoles by annulation of electron-rich anilines and quinones. Tetrahedron Letters, 57 (50). pp. 5653-5657. ISSN 0040-4039. https://resolver.caltech.edu/CaltechAUTHORS:20170103-154034263

Li, Jiaming and Grubbs, Robert H. and Stoltz, Brian M. (2016) Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate. Organic Letters, 18 (21). pp. 5449-5451. ISSN 1523-7060. PMCID PMC5512709. https://resolver.caltech.edu/CaltechAUTHORS:20161024-103416597

Kim, Kelly E. and Stoltz, Brian M. (2016) A Second-Generation Synthesis of the Cyanthiwigin Natural Product Core. Organic Letters, 18 (21). pp. 5720-5723. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20161024-113042085

Pritchett, Beau P. and Kikuchi, Jun and Numajiri, Yoshitaka et al. (2016) Enantioselective Pd-Catalyzed Allylic Alkylation Reactions of Dihydropyrido[1,2-a]indolone Substrates: Efficient Syntheses of (−)-Goniomitine, (+)-Aspidospermidine, and (−)-Quebrachamine. Angewandte Chemie International Edition, 55 (43). pp. 13529-13532. ISSN 1433-7851. PMCID PMC5207349. https://resolver.caltech.edu/CaltechAUTHORS:20160927-100108036

Kim, Kelly E. and Li, Jiaming and Grubbs, Robert H. et al. (2016) Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation. Journal of the American Chemical Society, 138 (40). pp. 13179-13182. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20161003-161852128

Krishnan, Subramanian and Chang, Alexander C. and Stoltz, Brian M. et al. (2016) Escherichia coli K1 Modulates Peroxisome Proliferator–Activated Receptor γ and Glucose Transporter 1 at the Blood-Brain Barrier in Neonatal Meningitis. Journal of Infectious Diseases, 214 (7). pp. 1092-1104. ISSN 0022-1899. PMCID PMC5021232. https://resolver.caltech.edu/CaltechAUTHORS:20170106-160004918

Mohr, Justin T. and Moore, Jared T. and Stoltz, Brian M. (2016) Enantioconvergent catalysis. Beilstein Journal of Organic Chemistry, 12 . pp. 2038-2045. ISSN 1860-5397. PMCID PMC5082454. https://resolver.caltech.edu/CaltechAUTHORS:20161006-142747894

Hethcox, J. Caleb and Shockley, Samantha E. and Stoltz, Brian M. (2016) Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates. ACS Catalysis, 6 (9). pp. 6207-6213. ISSN 2155-5435. PMCID PMC5481154. https://resolver.caltech.edu/CaltechAUTHORS:20160822-135959905

Toutov, Anton A. and Liu, Wen-Bo and Stoltz, Brian M. et al. (2016) Potassium tert-Butoxide-Catalyzed Dehydrogenative Cross-Coupling of Heteroarenes with Hydrosilanes. Organic Syntheses, 93 . pp. 263-271. ISSN 0078-6209. https://resolver.caltech.edu/CaltechAUTHORS:20160919-073857486

Hayashi, Masaki and Bachman, Shoshana and Hashimoto, Satoshi et al. (2016) Ni-Catalyzed Enantioselective C-Acylation of α-Substituted Lactams. Journal of the American Chemical Society, 138 (29). pp. 8997-9000. ISSN 0002-7863. PMCID PMC4963289. https://resolver.caltech.edu/CaltechAUTHORS:20160725-104304872

Craig, Robert A., II and Smith, Russell C. and Pritchett, Beau P. et al. (2016) Preparation of 1,5-Dioxaspiro[5.5]undecan-3-one. Organic Syntheses, 93 . pp. 210-227. ISSN 2333-3553. PMCID PMC5514842. https://resolver.caltech.edu/CaltechAUTHORS:20160919-074608608

Estipona, Benzi I. and Pritchett, Beau P. and Craig, Robert A. et al. (2016) Catalytic enantioselective total synthesis of (+)-eucomic acid. Tetrahedron, 72 (26). pp. 3707-3712. ISSN 0040-4020. PMCID PMC4986999. https://resolver.caltech.edu/CaltechAUTHORS:20160707-080125930

Stoltz, Brian M. and Martin, Stephen (2016) Tetrahedron Young Investigator Award ~ 2016. Tetrahedron, 72 (26). iii. ISSN 0040-4020. https://resolver.caltech.edu/CaltechAUTHORS:20160707-090355308

Wright, Austin C. and Haley, Christopher K. and Lapointe, Guillaume et al. (2016) Synthesis of Aryl Ketoamides via Aryne Insertion into Imides. Organic Letters, 18 (12). pp. 2793-2795. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20160609-145221780

Han, Seo-Jung and Doi, Ryohei and Stoltz, Brian M. (2016) Nickel-Catalyzed Intramolecular C−O Bond Formation: Synthesis of Cyclic Enol Ethers. Angewandte Chemie International Edition, 55 (26). pp. 7437-7440. ISSN 1433-7851. PMCID PMC4985346. https://resolver.caltech.edu/CaltechAUTHORS:20160510-141655234

O'Connor, Nicholas R. and Wood, John L. and Stoltz, Brian M. (2016) Synthetic Applications and Methodological Developments of Donor-Acceptor Cyclopropanes and Related Compounds. Israel Journal of Chemistry, 56 (6-7). pp. 431-444. ISSN 0021-2148. PMCID PMC6527366. https://resolver.caltech.edu/CaltechAUTHORS:20160202-091959130

Han, Seo-Jung and Stoltz, Brian M. (2016) A mild and efficient approach to enantioenriched α-hydroxyethyl α,β-unsaturated δ-lactams. Tetrahedron Letters, 57 (21). pp. 2233-2235. ISSN 0040-4039. PMCID PMC4864989. https://resolver.caltech.edu/CaltechAUTHORS:20160502-084148448

Liu, Wen-Bo and Okamoto, Noriko and Alexy, Eric J. et al. (2016) Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement. Journal of the American Chemical Society, 138 (16). pp. 5234-5237. ISSN 0002-7863. PMCID PMC5497580. https://resolver.caltech.edu/CaltechAUTHORS:20160427-092037065

Bagdanoff, Jeffrey T. and Behenna, Douglas C. and Stockdill, Jennifer L. et al. (2016) Enantioselective Synthesis of Caprolactam and Enone Precursors to the Heterocyclic DEFG Ring System of Zoanthenol. European Journal of Organic Chemistry, 2016 (12). pp. 2101-2104. ISSN 1434-193X. PMCID PMC5225988. https://resolver.caltech.edu/CaltechAUTHORS:20160425-132914132

O’Connor, Nicholas R. and Bolgar, Peter and Stoltz, Brian M. (2016) Development of a simple system for the oxidation of electron-rich diazo compounds to ketones. Tetrahedron Letters, 57 (8). pp. 849-851. ISSN 0040-4039. https://resolver.caltech.edu/CaltechAUTHORS:20160201-141332316

Bates, Kelvin H. and Nguyen, Tran B. and Teng, Alex P. et al. (2016) Production and Fate of C_4 Dihydroxycarbonyl Compounds from Isoprene Oxidation. Journal of Physical Chemistry A, 120 (1). pp. 106-117. ISSN 1089-5639. https://resolver.caltech.edu/CaltechAUTHORS:20160112-074404722

Su, Judith and Goldberg, Alexander F. G. and Stoltz, Brian M. (2016) Label-free detection of single nanoparticles and biological molecules using microtoroid optical resonators. Light: Science and Applications, 5 (1). Art. No. e16001. ISSN 2047-7538. PMCID PMC6059845. https://resolver.caltech.edu/CaltechAUTHORS:20160111-102110097

Korch, Katerina M. and Loskot, Steven A. and Stoltz, Brian M. (2016) Asymmetric Synthesis of Quaternary Stereocenters via Metal Enolates. In: PATAI'S Chemistry of Functional Groups. Wiley , Chichester, pp. 1-85. ISBN 9780470682531. https://resolver.caltech.edu/CaltechAUTHORS:20170919-091408635

2015

Liniger, Marc and VanderVelde, David G. and Takase, Michael K. et al. (2015) Total Synthesis and Characterization of 7-Hypoquinuclidonium Tetrafluoroborate and 7-Hypoquinuclidone BF_3 Complex. Journal of the American Chemical Society, 138 (3). pp. 969-974. ISSN 0002-7863. PMCID PMC4878439. https://resolver.caltech.edu/CaltechAUTHORS:20160119-141029568

Toutov, Anton A. and Liu, Wen-Bo and Betz, Kerry N. et al. (2015) Catalytic C–H bond silylation of aromatic heterocycles. Nature Protocols, 10 (12). pp. 1897-1903. ISSN 1754-2189. https://resolver.caltech.edu/CaltechAUTHORS:20151103-103452993

Craig, Robert A., II and Loskot, Steven A. and Mohr, Justin T. et al. (2015) Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones. Organic Letters, 17 (21). pp. 5160-5163. ISSN 1523-7060. PMCID PMC4640231. https://resolver.caltech.edu/CaltechAUTHORS:20151102-100307186

Liu, Yiyang and Virgil, Scott C. and Grubbs, Robert H. et al. (2015) Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (−)-Aspewentins A, B, and C. Angewandte Chemie International Edition, 54 (40). pp. 11800-11803. ISSN 1433-7851. PMCID PMC4686263. https://resolver.caltech.edu/CaltechAUTHORS:20150807-083400322

Kita, Yusuke and Numajiri, Yoshitaka and Okamoto, Noriko et al. (2015) Construction of Tertiary Chiral Centers by Pd-catalyzed Asymmetric Allylic Alkylation of Prochiral Enolate Equivalents. Tetrahedron, 71 (37). pp. 6349-6353. ISSN 0040-4020. PMCID PMC4528676. https://resolver.caltech.edu/CaltechAUTHORS:20150608-130804663

Xing, Xiangyou and O'Connor, Nicholas R. and Stoltz, Brian M. (2015) Palladium(II)-Catalyzed Allylic C-H Oxidation of Hindered Substrates Featuring Tunable Selectivity Over Extent of Oxidation. Angewandte Chemie International Edition, 54 (38). pp. 11186-11190. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20150807-090520766

Holder, Jeffrey C. and Goodman, Emmett D. and Kikushima, Kotaro et al. (2015) Synthesis of Diverse β-Quaternary Ketones via Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Cyclic Enones. Tetrahedron, 71 (35). pp. 5781-5792. ISSN 0040-4020. PMCID PMC4598955. https://resolver.caltech.edu/CaltechAUTHORS:20141208-091240402

Shockley, Samantha E. and Holder, Jeffrey C. and Stoltz, Brian M. (2015) Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Cyclic Electrophiles. Organic Process Research & Development, 19 (8). pp. 974-981. ISSN 1083-6160. PMCID PMC4896742. https://resolver.caltech.edu/CaltechAUTHORS:20150728-085152188

Holder, Jeffrey C. and Shockley, Samantha E. and Wiesenfeldt, Mario P. et al. (2015) Preparation of (S)-tert-ButylPyOx and Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids. Organic Syntheses, 92 . pp. 247-266. ISSN 2333-3553. PMCID PMC6499391. https://resolver.caltech.edu/CaltechAUTHORS:20150824-143923597

Craig, Robert A., II and Stoltz, Brian M. (2015) Synthesis and exploration of electronically modified (R)-5,5-dimethyl-(p-CF_3)_3-i-PrPHOX in palladium-catalyzed enantio- and diastereoselective allylic alkylation: a practical alternative to (R)-(p-CF_3)_3-t-BuPHOX. Tetrahedron Letters, 56 (32). pp. 4670-4673. ISSN 0040-4039. PMCID PMC4524747. https://resolver.caltech.edu/CaltechAUTHORS:20150706-103427588

Marziale, Alexander N. and Duquette, Douglas C. and Craig, Robert A., II et al. (2015) An Efficient Protocol for the Palladium-Catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst. Advanced Synthesis and Catalysis, 357 (10). pp. 2238-2245. ISSN 1615-4150. PMCID PMC4811629. https://resolver.caltech.edu/CaltechAUTHORS:20150720-144300390

Bergner, Magnus and Duquette, Douglas C. and Chio, Linda et al. (2015) Exceedingly Efficient Synthesis of (±)-Grandifloracin and Acylated Analogues. Organic Letters, 17 (12). pp. 3008-3010. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20150615-081527494

Goldberg, Alexander F. G. and Craig, Robert A., II and O'Connor, Nicholas R. et al. (2015) Highly functionalized donor–acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids. Tetrahedron Letters, 56 (23). pp. 2983-2990. ISSN 0040-4039. PMCID PMC4479304. https://resolver.caltech.edu/CaltechAUTHORS:20140930-130037903

Lee, Chung Whan and Han, Seo-Jung and Virgil, Scott C. et al. (2015) Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters. Tetrahedron, 71 (22). pp. 3666-3670. ISSN 0040-4020. PMCID PMC4429905. https://resolver.caltech.edu/CaltechAUTHORS:20141110-091731285

Numajiri, Yoshitaka and Jiménez-Osés, Gonzalo and Wang, Bo et al. (2015) Enantioselective Synthesis of Dialkylated N-Heterocycles by Palladium-Catalyzed Allylic Alkylation. Organic Letters, 17 (5). pp. 1082-1085. ISSN 1523-7060. PMCID PMC6410707. https://resolver.caltech.edu/CaltechAUTHORS:20150302-135348269

Boeser, Cornelia L. and Holder, Jeffrey C. and Taylor, Buck L. H. et al. (2015) Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones. Chemical Science, 6 (3). pp. 1917-1922. ISSN 2041-6520. PMCID PMC4338963. https://resolver.caltech.edu/CaltechAUTHORS:20150313-143109436

Li, Zining and Geng, Qian and Lv, Zhe et al. (2015) Selective syntheses of leuconolam, leuconoxine, and mersicarpine alkaloids from a common intermediate through regiocontrolled cyclizations by Staudinger reactions. Organic Chemistry Frontiers, 2 (3). pp. 236-240. ISSN 2052-4110. PMCID PMC4333676. https://resolver.caltech.edu/CaltechAUTHORS:20150303-082954224

Liu, Yiyang and Han, Seo-Jung and Liu, Wen-Bo et al. (2015) Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules. Accounts of Chemical Research, 48 (3). pp. 740-751. ISSN 0001-4842. PMCID PMC6410712. https://resolver.caltech.edu/CaltechAUTHORS:20150302-110204535

Toutov, Anton A. and Liu, Wen-Bo and Betz, Kerry N. et al. (2015) Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst. Nature, 518 (7537). pp. 80-84. ISSN 0028-0836. https://resolver.caltech.edu/CaltechAUTHORS:20141118-102135823

Numajiri, Yoshitaka and Pritchett, Beau P. and Chiyoda, Koji et al. (2015) Enantioselective Synthesis of α‑Quaternary Mannich Adducts by Palladium-Catalyzed Allylic Alkylation: Total Synthesis of (+)-Sibirinine. Journal of the American Chemical Society, 137 (3). pp. 1040-1043. ISSN 0002-7863. PMCID PMC4311947. https://resolver.caltech.edu/CaltechAUTHORS:20150126-101327424

Korch, Katerina M. and Eidamshaus, Christian and Behenna, Douglas C. et al. (2015) Enantioselective Synthesis of α-Secondary and α-Tertiary Piperazin-2-ones and Piperazines by Catalytic Asymmetric Allylic Alkylation. Angewandte Chemie International Edition, 54 (1). pp. 179-183. ISSN 1433-7851. PMCID PMC4285707. https://resolver.caltech.edu/CaltechAUTHORS:20141117-092808886

Han, Seo-Jung and Vogt, Florian and May, Jeremy A. et al. (2015) Evolution of a Unified, Stereodivergent Approach to the Synthesis of Communesin F and Perophoramidine. Journal of Organic Chemistry, 80 (1). pp. 528-547. ISSN 0022-3263. PMCID PMC4285143. https://resolver.caltech.edu/CaltechAUTHORS:20141202-144818205

2014

Shockley, Samantha E. and Holder, Jeffrey C. and Stoltz, Brian M. (2014) A Catalytic, Enantioselective Formal Synthesis of (+)-Dichroanone and (+)-Taiwaniaquinone H. Organic Letters, 16 (24). pp. 6362-6365. ISSN 1523-7060. PMCID PMC4275150. https://resolver.caltech.edu/CaltechAUTHORS:20141215-090404543

Han, Seo-Jung and de Melo, Gabriel Fernando and Stoltz, Brian M. (2014) A new method for the cleavage of nitrobenzyl amides and ethers. Tetrahedron Letters, 55 (47). pp. 6467-6469. ISSN 0040-4039. PMCID PMC4228375. https://resolver.caltech.edu/CaltechAUTHORS:20141020-152334369

Liu, Yiyang and Liniger, Marc and McFadden, Ryan M. et al. (2014) Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation. Beilstein Journal of Organic Chemistry, 10 . pp. 2501-2512. ISSN 1860-5397. PMCID PMC4222294. https://resolver.caltech.edu/CaltechAUTHORS:20141215-084337170

Gordon, Jonny R. and Nelson, Hosea M. and Virgil, Scott C. et al. (2014) The Total Syntheses of Basiliolide C, epi-Basiliolide C, and Protecting-Group-Free Total Syntheses of Transtaganolides C and D. Journal of Organic Chemistry, 79 (20). pp. 9740-9747. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20141015-093052860

Bhat, Vikram and Virgil, Scott C. and Stoltz, Brian M. (2014) Asymmetric synthesis of QUINAP via dynamic kinetic resolution. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140811-150157474

Holder, Jeffrey C. and Shockley, Samantha E. and Marziale, Alexander N. et al. (2014) Development and application of a palladium-​catalyzed enantioselective conjugate addition. In: 248th American Chemical Society National Meeting & Exposition, August 10-14, 2014, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20140811-150326033

Ma, Sandy and Reeves, Corey M. and Craig, Robert A., II et al. (2014) Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters. Tetrahedron, 70 (27-28). pp. 4208-4212. ISSN 0040-4020. PMCID PMC4078409. https://resolver.caltech.edu/CaltechAUTHORS:20140421-084129624

Han, Seo-Jung and Vogt, Florian and Krishnan, Shyam et al. (2014) A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine. Organic Letters, 16 (12). pp. 3316-3319. ISSN 1523-7060. PMCID PMC4068777. https://resolver.caltech.edu/CaltechAUTHORS:20140616-094313057

Hong, Allen Y. and Stoltz, Brian M. (2014) Biosynthesis and Chemical Synthesis of Presilphiperfolanol Natural Products. Angewandte Chemie International Edition, 53 (21). pp. 5248-5260. ISSN 1433-7851. PMCID PMC4334158. https://resolver.caltech.edu/CaltechAUTHORS:20140505-091759313

Reeves, Corey M. and Behenna, Douglas C. and Stoltz, Brian M. (2014) Development of (Trimethylsilyl)ethyl Ester Protected Enolates and Applications in Palladium-Catalyzed Enantioselective Allylic Alkylation: Intermolecular Cross-Coupling of Functionalized Electrophiles. Organic Letters, 16 (9). pp. 2314-2317. ISSN 1523-7060. PMCID PMC4011571. https://resolver.caltech.edu/CaltechAUTHORS:20140424-145313873

Craig, Robert A., II and O'Connor, Nicholas R. and Goldberg, Alexander F. G. et al. (2014) Stereoselective Lewis Acid Mediated (3+2) Cycloadditions of N-H- and N-Sulfonylaziridines with Heterocumulenes. Chemistry: a European Journal, 20 (16). pp. 4806-4813. ISSN 0947-6539. PMCID PMC4104980. https://resolver.caltech.edu/CaltechAUTHORS:20140310-100420677

Jones, Amanda C. and May, Jeremy A. and Sarpong, Richmond et al. (2014) Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements. Angewandte Chemie International Edition, 53 (10). pp. 2556-2591. ISSN 1433-7851. PMCID PMC4030764. https://resolver.caltech.edu/CaltechAUTHORS:20140501-092433445

Bates, Kelvin H. and Crounse, John D. and St. Clair, Jason M. et al. (2014) Gas Phase Production and Loss of Isoprene Epoxydiols. Journal of Physical Chemistry A, 118 (7). pp. 1237-1246. ISSN 1089-5639. https://resolver.caltech.edu/CaltechAUTHORS:20140210-145231305

Krishnan, Subramanian and Shanmuganathan, Muthusamy V. and Behenna, Douglas et al. (2014) Angiotensin II Receptor Type 1—A Novel Target for Preventing Neonatal Meningitis in Mice by Escherichia coli K1. Journal of Infectious Diseases, 209 (3). pp. 409-419. ISSN 0022-1899. PMCID PMC3883175. https://resolver.caltech.edu/CaltechAUTHORS:20140214-093051277

Liu, Yiyang and Kim, Kelly E. and Herbert, Myles B. et al. (2014) Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins. Advanced Synthesis and Catalysis, 356 (1). pp. 130-136. ISSN 1615-4150. PMCID PMC3998208. https://resolver.caltech.edu/CaltechAUTHORS:20140122-135551444

Stoltz, B. M. and Bennett, N. B. and Duquette, D. C. et al. (2014) Alkylations of Enols and Enolates. In: Comprehensive Organic Synthesis II. Vol.3. Elsevier , Amsterdam, pp. 1-55. ISBN 978-0-08-097743-0. https://resolver.caltech.edu/CaltechAUTHORS:20150126-091231023

2013

Bennett, Nathan B. and Stoltz, Brian M. (2013) A Unified Approach to the Daucane and Sphenolobane Bicyclo[5.3.0]decane Core: Enantioselective Total Syntheses of Daucene, Daucenal, Epoxydaucenal B, and 14-para-Anisoyloxydauc-4,8-diene. Chemistry: a European Journal, 19 (52). pp. 17745-17750. ISSN 0947-6539. PMCID PMC3927641. https://resolver.caltech.edu/CaltechAUTHORS:20131209-101849386

Liu, Wen-Bo and Reeves, Corey M. and Stoltz, Brian M. (2013) Enantio-, Diastereo-, and Regioselective Iridium-Catalyzed Asymmetric Allylic Alkylation of Acyclic β-Ketoesters. Journal of the American Chemical Society, 135 (46). pp. 17298-17301. ISSN 0002-7863. PMCID PMC3881553. https://resolver.caltech.edu/CaltechAUTHORS:20140106-104251997

Bhat, Vikram and Wang, Su and Stoltz, Brian M. et al. (2013) Asymmetric Synthesis of QUINAP via Dynamic Kinetic Resolution. Journal of the American Chemical Society, 135 (45). pp. 16829-16832. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20131108-073355250

Holder, Jeffrey C. and Zou, Lufeng and Marziale, Alexander N. et al. (2013) Mechanism and Enantioselectivity in Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β‑Substituted Cyclic Enones: Insights from Computation and Experiment. Journal of the American Chemical Society, 135 (40). pp. 14996-15007. ISSN 0002-7863. PMCID PMC3846424. https://resolver.caltech.edu/CaltechAUTHORS:20131105-114622242

Meyer, Michael E. and Phillips, John H. and Ferreira, Eric M. et al. (2013) Use of a palladium(II)-catalyzed oxidative kinetic resolution in synthetic efforts toward bielschowskysin. Tetrahedron, 69 (36). pp. 7627-7635. ISSN 0040-4020. PMCID PMC3728638. https://resolver.caltech.edu/CaltechAUTHORS:20131003-103642590

Shimizu, Hideki and Holder, Jeffrey C. and Stoltz, Brian M. (2013) A scalable synthesis of the (S)-4-(tert-butyl)-2-(pyridin-2-yl)-4,5-dihydrooxazole ((S)-t-BuPyOx) ligand. Beilstein Journal of Organic Chemistry, 9 . pp. 1637-1642. ISSN 1860-5397. PMCID PMC3778391. https://resolver.caltech.edu/CaltechAUTHORS:20130906-155635457

Liu, Wen-Bo and Reeves, Corey M. and Virgil, Scott C. et al. (2013) Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters via Ir-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation and Applications in Sequential Pd Catalysis. Journal of the American Chemical Society, 135 (29). pp. 10626-10629. ISSN 0002-7863. PMCID PMC3756902. https://resolver.caltech.edu/CaltechAUTHORS:20131002-102340513

Haley, Christopher K. and Gilmore, Christopher D. and Stoltz, Brian M. (2013) Development of a palladium-catalyzed decarboxylative cross-coupling of (2-azaaryl)carboxylates with aryl halides. Tetrahedron, 69 (27-28). pp. 5732-5736. ISSN 0040-4020. PMCID PMC3686134. https://resolver.caltech.edu/CaltechAUTHORS:20130802-141019170

Shibuya, Grant M. and Enquist, John A., Jr. and Stoltz, Brian M. (2013) Enantioselective Synthesis of the 5–6–7 Carbocyclic Core of the Gagunin Diterpenoids. Organic Letters, 15 (13). pp. 3480-3483. ISSN 1523-7060. PMCID PMC3743267. https://resolver.caltech.edu/CaltechAUTHORS:20130813-101335730

Vieregg, Jeffrey R. and Nelson, Hosea M. and Stoltz, Brian M. et al. (2013) Selective Nucleic Acid Capture with Shielded Covalent Probes. Journal of the American Chemical Society, 135 (26). pp. 9691-9699. ISSN 0002-7863. PMCID PMC3703666. https://resolver.caltech.edu/CaltechAUTHORS:20130905-155148025

Reeves, Corey M. and Eidamshaus, Christian and Kim, Jimin et al. (2013) Enantioselective Construction of α-Quaternary Cyclobutanones by Catalytic Asymmetric Allylic Alkylation. Angewandte Chemie International Edition, 52 (26). pp. 6718-6721. ISSN 1433-7851. PMCID PMC3817853. https://resolver.caltech.edu/CaltechAUTHORS:20130809-133957166

Nelson, Hosea M. and Gordon, Jonny R. and Virgil, Scott C. et al. (2013) Total Syntheses of (-)-Transtaganolide A, (+)-Transtaganolide B, (+)-Transtaganolide C, and (-)-Transtaganolide D and Biosynthetic Implications. Angewandte Chemie International Edition, 52 (26). pp. 6699-6703. ISSN 1433-7851. PMCID PMC3825171. https://resolver.caltech.edu/CaltechAUTHORS:20130809-132636851

Hong, Allen Y. and Stoltz, Brian M. (2013) The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis. European Journal of Organic Chemistry, 2013 (14). pp. 2745-2759. ISSN 1434-193X. PMCID PMC4059687. https://resolver.caltech.edu/CaltechAUTHORS:20130620-142930731

Holder, Jeffrey C. and Kikushima, Kotaro and Marziale, Alexander N. et al. (2013) Development of a palladium-catalyzed enantioselective conjugate addition of arylboronic acids to cyclic conjugate acceptors. In: 245th ACS National Meeting & Exposition, Abstracts of Papers, April 7-11, 2013, New Orleans, LA. https://resolver.caltech.edu/CaltechAUTHORS:20130410-144615697

Bennett, Nathan B. and Duquette, Douglas C. and Kim, Jimin et al. (2013) Expanding Insight into Asymmetric Palladium-Catalyzed Allylic Alkylation of N-Heterocyclic Molecules and Cyclic Ketones. Chemistry: a European Journal, 19 (14). pp. 4414-4418. ISSN 0947-6539. PMCID PMC3815597. https://resolver.caltech.edu/CaltechAUTHORS:20130501-072844784

Su, Judith and Goldberg, Alex and Raubitschek, Andrew et al. (2013) Frequency Locked Microtoroid Optical Resonators as a Non-Invasive Tumor Biopsy Alternative. Biophysical Journal, 104 (2). 528A. ISSN 0006-3495. https://resolver.caltech.edu/CaltechAUTHORS:20130501-082658216

Holder, Jeffrey C. and Marziale, Alexander N. and Gatti, Michele et al. (2013) Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Heterocyclic Acceptors. Chemistry: a European Journal, 19 (1). pp. 74-77. ISSN 0947-6539. PMCID PMC3753812. https://resolver.caltech.edu/CaltechAUTHORS:20130212-115138312

2012

Caspi, Daniel D. and Zhang, Haiming and Virgil, Scott C. et al. (2012) Rapid and Convergent Synthesis of a 2,4’-Linked Tri-oxazole in an Approach to Poly-oxazoles. Heterocycles, 86 (2). pp. 1003-1008. ISSN 0385-5414. https://resolver.caltech.edu/CaltechAUTHORS:20130308-082047917

Keith, John A. and Behenna, Douglas C. and Sherden, Nathaniel H. et al. (2012) The Reaction Mechanism of the Enantioselective Tsuji Allylation: Inner-Sphere and Outer-Sphere Pathways, Internal Rearrangements, and Asymmetric C–C Bond Formation. Journal of the American Chemical Society, 134 (46). pp. 19050-19060. ISSN 0002-7863. PMCID PMC3537505. https://resolver.caltech.edu/CaltechAUTHORS:20130114-141639858

Craig, Robert A., II and Roizen, Jennifer L. and Smith, Russell C. et al. (2012) Enantioselective Synthesis of a Hydroxymethyl-cis-1,3-cyclopentenediol Building Block. Organic Letters, 14 (22). pp. 5716-5719. ISSN 1523-7060. PMCID PMC3506031. https://resolver.caltech.edu/CaltechAUTHORS:20130107-104400691

Reeves, Corey M. and Stoltz, Brian M. (2012) Catalytic Enantioselective Alkylation of Prochiral Ketone Enolates. In: Asymmetric Synthesis II: More Methods and Applications. Wiley , Weinheim, pp. 1-10. ISBN 9783527329212. https://resolver.caltech.edu/CaltechAUTHORS:20130415-152954275

Goldberg, Alexander F. G. and O’Connor, Nicholas R. and Craig, Robert A., II et al. (2012) Lewis Acid Mediated (3 + 2) Cycloadditions of Donor–Acceptor Cyclopropanes with Heterocumulenes. Organic Letters, 14 (20). pp. 5314-5317. ISSN 1523-7060. PMCID PMC3490221. https://resolver.caltech.edu/CaltechAUTHORS:20121203-103554504

Hong, Allen Y. and Stoltz, Brian M. (2012) Enantioselective Total Synthesis of the Reported Structures of (−)-9-epi-Presilphiperfolan-1-ol and (−)-Presilphiperfolan-1-ol: Structural Confirmation and Reassignment and Biosynthetic Insights. Angewandte Chemie International Edition, 51 (38). pp. 9674-9678. ISSN 1433-7851. PMCID PMC3517068. https://resolver.caltech.edu/CaltechAUTHORS:20141217-142148376

Kim, Jimin and Stoltz, Brian M. (2012) A C–N insertion of β-lactam to benzyne: unusual formation of acridone. Tetrahedron Letters, 53 (37). pp. 4994-4996. ISSN 0040-4039. https://resolver.caltech.edu/CaltechAUTHORS:20121029-133109161

Behenna, Douglas C. and Stoltz, Brian M. (2012) Natural Products as Inspiration for Reaction Development: Catalytic Enantioselective Decarboxylative Reactions of Prochiral Enolate Equivalents. In: Inventing reactions. Topics in organometallic chemistry. No.44. Springer-Verlag , Berlin, pp. 281-314. ISBN 978-3-642-34285-1. https://resolver.caltech.edu/CaltechAUTHORS:20130516-140126410

Stoltz, Brian M. (2012) Novel approach to antitumor antibiotics: Using the power of benzyne in synthesis. In: ACS National Meeting & Exposition, August 19-23, 2012, Philadelphia, PA. https://resolver.caltech.edu/CaltechAUTHORS:20120822-092222870

Vieregg, Jeffrey R. and Nelson, Hosea and Stoltz, Brian et al. (2012) Sensitive and selective nucleic acid capture with shielded covalent probes. In: 244th ACS National Meeting & Exposition, August 19-23, 2012, Philadelphia, PA. https://resolver.caltech.edu/CaltechAUTHORS:20120822-154455462

Tadross, Pamela M. and Stoltz, Brian M. (2012) A Comprehensive History of Arynes in Natural Product Total Synthesis. Chemical Reviews, 112 (6). pp. 3550-3577. ISSN 0009-2665. https://resolver.caltech.edu/CaltechAUTHORS:20120712-093347151

Behenna, Douglas C. and Liu, Yiyang and Yurino, Taiga et al. (2012) Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams. Nature Chemistry, 4 (2). pp. 130-133. ISSN 1755-4330. PMCID PMC3266627. https://resolver.caltech.edu/CaltechAUTHORS:20120126-101327960

Bennett, Nathan B. and Hong, Allen Y. and Harned, Andrew M. et al. (2012) Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork–Danheiser approach: preparation of mono-, bi-, and tricyclic systems. Organic and Biomolecular Chemistry, 10 (1). pp. 56-59. ISSN 1477-0520. PMCID PMC3365663. https://resolver.caltech.edu/CaltechAUTHORS:20111021-144400118

2011

Hong, Allen Y. and Bennett, Nathan B. and Krout, Michael R. et al. (2011) Palladium-catalyzed asymmetric alkylation in the synthesis of cyclopentanoid and cycloheptanoid core structures bearing all-carbon quaternary stereocenters. Tetrahedron, 67 (52). pp. 10234-10248. ISSN 0040-4020. PMCID PMC3279929. https://resolver.caltech.edu/CaltechAUTHORS:20120124-111234894

Behenna, Douglas C. and Mohr, Justin T. and Sherden, Nathaniel H. et al. (2011) Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies. Chemistry: a European Journal, 17 (50). pp. 14199-14223. ISSN 0947-6539. PMCID PMC3365686. https://resolver.caltech.edu/CaltechAUTHORS:20120214-111558996

Enquist, John A., Jr. and Virgil, Scot C. and Stoltz, Brian M. (2011) Total Syntheses of Cyanthiwigins B, F, and G. Chemistry: a European Journal, 17 (36). pp. 9957-9969. ISSN 0947-6539. PMCID PMC3365662. https://resolver.caltech.edu/CaltechAUTHORS:20111107-115520974

Goldberg, Alexander F. G. and Stoltz, Brian M. (2011) A Palladium-Catalyzed Vinylcyclopropane (3 + 2) Cycloaddition Approach to the Melodinus Alkaloids. Organic Letters, 13 (16). pp. 4474-4476. ISSN 1523-7060. PMCID PMC3155617. https://resolver.caltech.edu/CaltechAUTHORS:20110912-114011217

Tadross, Pamela M. and Bugga, Pradeep and Stoltz, Brian M. (2011) A rapid and convergent synthesis of the integrastatin core. Organic and Biomolecular Chemistry, 9 (15). pp. 5354-5357. ISSN 1477-0520. https://resolver.caltech.edu/CaltechAUTHORS:20110808-112210599

Day, Joshua J. and McFadden, Ryan M. and Virgil, Scott C. et al. (2011) The Catalytic Enantioselective Total Synthesis of (+)-Liphagal. Angewandte Chemie International Edition, 50 (30). pp. 6814-6818. ISSN 1433-7851. PMCID PMC3361906. https://resolver.caltech.edu/CaltechAUTHORS:20110622-115436125

Petersen, Kimberly S. and Stoltz, Brian M. (2011) Palladium-catalyzed, asymmetric Baeyer–Villiger oxidation of prochiral cyclobutanones with PHOX ligands. Tetrahedron, 67 (24). pp. 4352-4357. ISSN 0040-4020. https://resolver.caltech.edu/CaltechAUTHORS:20110706-135043254

Kikushima, Kotaro and Holder, Jeffrey C. and Gatti, Michele et al. (2011) Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Five-, Six-, and Seven-Membered β-Substituted Cyclic Enones: Enantioselective Construction of All-Carbon Quaternary Stereocenters. Journal of the American Chemical Society, 133 (18). pp. 6902-6905. ISSN 0002-7863. PMCID PMC3087848. https://resolver.caltech.edu/CaltechAUTHORS:20110608-104503600

Allan, Kevin M. and Gilmore, Christopher D. and Stoltz, Brian M. (2011) Benzannulated Bicycles by Three-Component Aryne Reactions. Angewandte Chemie International Edition, 50 (19). pp. 4488-4491. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20110606-080601724

Behenna, Douglas C. and Krishnan, Shyam and Stoltz, Brian M. (2011) Confirmation of the absolute configuration of (-)-aurantioclavine. Tetrahedron Letters, 52 (17). pp. 2152-2154. ISSN 0040-4039. https://resolver.caltech.edu/CaltechAUTHORS:20110526-081657895

Nelson, Hosea M. and Murakami, Kei and Virgil, Scott C. et al. (2011) A General Approach to the Basiliolide/Transtaganolide Natural Products: Total Syntheses of Basiliolide B, epi-8-Basiliolide B, Transtaganolide C, and Transtaganolide D. Angewandte Chemie International Edition, 50 (16). pp. 3688-3691. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20110404-113128218

Chou, Tsui-Fen and Brown, Steve J. and Minond, Dmitriy et al. (2011) Reversible inhibitor of p97, DBeQ, impairs both ubiquitin-dependent and autophagic protein clearance pathways. Proceedings of the National Academy of Sciences of the United States of America, 108 (12). pp. 4834-4839. ISSN 0027-8424. PMCID PMC3064330. https://resolver.caltech.edu/CaltechAUTHORS:20110414-085357247

Hong, Allen Y. and Krout, Michael R. and Jensen, Thomas et al. (2011) Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes. Angewandte Chemie International Edition, 50 (12). pp. 2756-2760. ISSN 1433-7851. PMCID PMC3365661. https://resolver.caltech.edu/CaltechAUTHORS:20110329-133407762

Mukherjee, Herschel and McDougal, Nolan T. and Virgil, Scott C. et al. (2011) A Catalytic, Asymmetric Formal Synthesis of (+)-Hamigeran B. Organic Letters, 13 (5). pp. 825-827. ISSN 1523-7060. PMCID PMC3045637. https://resolver.caltech.edu/CaltechAUTHORS:20110201-085102866

2010

Stoltz, B. M. (2010) Complex natural products as a driving force for discovery in organic chemistry. In: International Chemical Congress of Pacific Basin Societies (Pacifichem 2010), December 15-20, 2010, Honolulu, HI. https://resolver.caltech.edu/CaltechAUTHORS:20120816-071730866

Stoltz, B. M. (2010) Intertwined nature of chemical synthesis and the discovery process. In: International Chemical Congress of Pacific Basin Societies (Pacifichem 2010), December 15-20, 2010, Honolulu, HI. https://resolver.caltech.edu/CaltechAUTHORS:20120815-153559315

McDougal, Nolan T. and Streuff, Jan and Mukherjee, Herschel et al. (2010) Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides. Tetrahedron Letters, 51 (42). pp. 5550-5554. ISSN 0040-4039. PMCID PMC2976555. https://resolver.caltech.edu/CaltechAUTHORS:20101103-104745366

Freeman, David B. and Holubec, Alexandra A. and Weiss, Matthew W. et al. (2010) Welwitindolinone C synthetic studies. Construction of the welwitindolinone carbon skeleton via a transannular nitrone cycloaddition. Tetrahedron, 66 (33). pp. 6647-6655. ISSN 0040-4020. PMCID PMC2924776. https://resolver.caltech.edu/CaltechAUTHORS:20141217-164835707

McDougal, Nolan T. and Virgil, Scott C. and Stoltz, Brian M. (2010) High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates. Synlett, 2010 (11). pp. 1712-1716. ISSN 0936-5214. PMCID PMC2976558. https://resolver.caltech.edu/CaltechAUTHORS:20100713-135750673

Baumgartner, Corinne and Ma, Sandy and Liu, Qi et al. (2010) Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis. Organic and Biomolecular Chemistry, 8 (13). pp. 2915-2917. ISSN 1477-0520. https://resolver.caltech.edu/CaltechAUTHORS:20100601-110245242

White, David E. and Stewart, Ian C. and Seashore-Ludlow, Brinton A. et al. (2010) A general enantioselective route to the chamigrene natural product family. Tetrahedron, 66 (26). 4668-4686 . ISSN 0040-4020. PMCID PMC2925317. https://resolver.caltech.edu/CaltechAUTHORS:20100712-150605717

Fulmer, Gregory R. and Miller, Alexander J. M. and Sherden, Nathaniel H. et al. (2010) NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist. Organometallics, 29 (9). pp. 2176-2179. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20100527-094834306

Tadross, Pamela M. and Virgil, Scott C. and Stoltz, Brian M. (2010) Aryne Acyl-Alkylation in the General and Convergent Synthesis of Benzannulated Macrolactone Natural Products: An Enantioselective Synthesis of (−)-Curvularin. Organic Letters, 12 (7). pp. 1612-1614. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20100413-105259618

Tadross, Pamela M. and Gilmore, Christopher D. and Bugga, Pradeep et al. (2010) Regioselective Reactions of Highly Substituted Arynes. Organic Letters, 12 (6). pp. 1224-1227. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20100405-115154177

Streuff, Jan and White, David E. and Virgil, Scott C. et al. (2010) A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres. Nature Chemistry, 2 (3). pp. 192-196. ISSN 1755-4330. PMCID PMC2917108. https://resolver.caltech.edu/CaltechAUTHORS:20100305-152223080

2009

Allan, Kevin M. and Hong, Boram D. and Stoltz, Brian M. (2009) Expedient synthesis of 3-hydroxyisoquinolines and 2-hydroxy-1,4-naphthoquinones via one-pot aryne acyl-alkylation/condensation. Organic and Biomolecular Chemistry, 7 (23). pp. 4960-4964. ISSN 1477-0520. https://resolver.caltech.edu/CaltechAUTHORS:20091214-081131773

Ebner, David C. and Bagdanoff, Jeffrey T. and Ferreira, Eric M. et al. (2009) The Palladium-Catalyzed Aerobic Kinetic Resolution of Secondary Alcohols: Reaction Development, Scope, and Applications. Chemistry: a European Journal, 15 (47). pp. 12978-12992. ISSN 0947-6539. PMCID PMC2862982. https://resolver.caltech.edu/CaltechAUTHORS:20100218-140616247

Ma, Sandy and Han, Xiaoqing and Krishnan, Shyam et al. (2009) Catalytic Enantioselective Stereoablative Alkylation of 3-Halooxindoles: Facile Access to Oxindoles with C3 All-Carbon Quaternary Stereocenters. Angewandte Chemie International Edition, 48 (1). pp. 1-6. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20091002-090709845

Sherden, Nathaniel H. and Behenna, Douglas C. and Virgil, Scott C. et al. (2009) Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Allylic Alkylation Reactions of Ketones. Angewandte Chemie International Edition, 48 (37). pp. 6840-6843. ISSN 1433-7851. PMCID PMC2880474. https://resolver.caltech.edu/CaltechAUTHORS:20091012-124240065

Stockdill, Jennifer L. and Behenna, Douglas C. and McClory, Andrew et al. (2009) An efficient synthesis of the carbocyclic core of zoanthenol. Tetrahedron, 65 (33). pp. 6571-6575. ISSN 0040-4020. https://resolver.caltech.edu/CaltechAUTHORS:20090817-150141765

Mohr, Justin T. and Hong, Allen Y. and Stoltz, Brian M. (2009) Enantioselective protonation. Nature Chemistry, 1 (5). pp. 359-369. ISSN 1755-4330. PMCID PMC2860147. https://resolver.caltech.edu/CaltechAUTHORS:20090828-231033230

Stockdill, Jennifer L. and Behenna, Douglas C. and Stoltz, Brian M. (2009) Unexpected decarbonylation during an acid-mediated cyclization to access the carbocyclic core of zoanthenol. Tetrahedron Letters, 50 (26). pp. 3182-3184. ISSN 0040-4039. https://resolver.caltech.edu/CaltechAUTHORS:20090909-132757912

Enquist, John A. and Stoltz, Brian M. (2009) Synthetic efforts toward cyathane diterpenoid natural products. Natural Product Reports, 26 (5). pp. 661-680. ISSN 0265-0568. PMCID PMC2683363. https://resolver.caltech.edu/CaltechAUTHORS:20090728-105816044

Nelson, Hosea M. and Stoltz, Brian M. (2009) Progress toward the synthesis of the transtaganolide/basiliolide natural products: an Ireland–Claisen approach. Tetrahedron Letters, 50 (15). pp. 1699-1701. ISSN 0040-4039. https://resolver.caltech.edu/CaltechAUTHORS:20090914-100459696

Sun, Qingyu and Nelson, Hosea and Ly, Tony et al. (2009) Side chain chemistry mediates backbone fragmentation in hydrogen deficient peptide radicals. Journal of Proteome Research, 8 (2). pp. 958-966. ISSN 1535-3893. https://resolver.caltech.edu/CaltechAUTHORS:20090630-151621799

Ebner, David C. and Tambar, Uttam K. and Stoltz, Brian M. (2009) The direct acyl-alkylation of arynes. Preparation of methyl 2-(2-acetylphenyl)acetate. Organic Syntheses, 86 . pp. 161-171. ISSN 2333-3553. https://resolver.caltech.edu/CaltechAUTHORS:20190903-130240760

Levine, Samantha R. and Krout, Michael R. and Stoltz, Brian M. (2009) Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone. Organic Letters, 11 (2). pp. 289-292. ISSN 1523-7060. PMCID PMC2724392. https://resolver.caltech.edu/CaltechAUTHORS:LEVol09

Petrova, Krastina V. and Mohr, Justin T. and Stoltz, Brian M. (2009) Enantioselective Total Synthesis of (+)-Cassiol. Organic Letters, 11 (2). pp. 293-295. ISSN 1523-7060. PMCID PMC2707596. https://resolver.caltech.edu/CaltechAUTHORS:PETol09

Mohr, Justin T. and Krout, Michael R. and Stoltz, Brian M. (2009) Preparation of (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-). Organic Syntheses, 86 . pp. 194-211. ISSN 0078-6209. PMCID PMC3011275. https://resolver.caltech.edu/CaltechAUTHORS:20150106-134315572

Stoltz, Brian M. and Krout, Michael R. and Mohr, Justin T. et al. (2009) Preparation of (S)-tert-ButylPHOX (Oxazole, 4-(1,1-dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro- (4S)-). Organic Syntheses, 86 . pp. 181-193. ISSN 0078-6209. PMCID PMC2805096. https://resolver.caltech.edu/CaltechAUTHORS:20141223-105727889

2008

Trend, Raissa M. and Stoltz, Brian M. (2008) Structural features and reactivity of (sparteine)PdCl_2: a model for selectivity in the oxidative kinetic resolution of secondary alcohols. Journal of the American Chemical Society, 130 (47). pp. 15957-15966. ISSN 0002-7863. PMCID PMC2649720. https://resolver.caltech.edu/CaltechAUTHORS:20090728-134418790

Allan, Kevin M. and Stoltz, Brian M. (2008) A concise total synthesis of (−)-quinocarcin via aryne annulation. Journal of the American Chemical Society, 130 (51). pp. 17270-17271. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20090804-102608108

Krishnan, Shyam and Bagdanoff, Jeffrey T. and Ebner, David C. et al. (2008) Pd-catalyzed enantioselective aerobic oxidation of secondary alcohols: Applications to the total synthesis of alkaloids. Journal of the American Chemical Society, 130 (41). pp. 13745-13754. ISSN 0002-7863. PMCID PMC2574996 . https://resolver.caltech.edu/CaltechAUTHORS:KRIjacs08

Mohr, Justin T. and Krout, Michael R. and Stoltz, Brian M. (2008) Natural products as inspiration for the development of asymmetric catalysis. Nature, 455 (7211). pp. 323-332. ISSN 0028-0836. PMCID PMC2562237. https://resolver.caltech.edu/CaltechAUTHORS:MOHnat08

Seto, Masaki and Roizen, Jennifer L. and Stoltz, Brian M. (2008) Catalytic Enantioselective Alkylation of Substituted Dioxanone Enol Ethers: Ready Access to C(α)-Tetrasubstituted Hydroxyketones, Acids, and Esters. Angewandte Chemie International Edition, 47 (36). pp. 6873-6876. ISSN 1433-7851. PMCID PMC2762748. https://resolver.caltech.edu/CaltechAUTHORS:20170215-154336630

Ebner, David C. and Trend, Raissa M. and Genet, Cédric et al. (2008) Palladium-Catalyzed Enantioselective Oxidation of Chiral Secondary Alcohols: Access to Both Enantiomeric Series. Angewandte Chemie International Edition, 47 (34). pp. 6367-6370. ISSN 14337851. PMCID PMC2790069. https://resolver.caltech.edu/CaltechAUTHORS:20170215-152617371

Enquist, John A., Jr. and Stoltz, Brian M. (2008) The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation. Nature, 453 (7199). pp. 1228-1231. ISSN 0028-0836. PMCID PMC2474750. https://resolver.caltech.edu/CaltechAUTHORS:20170216-150759253

Ferreira, Eric M. and Zhang, Haiming and Stoltz, Brian M. (2008) C–H bond functionalizations with palladium(II): intramolecular oxidative annulations of arenes. Tetrahedron, 64 (26). pp. 5987-6001. ISSN 0040-4020. PMCID PMC2441596. https://resolver.caltech.edu/CaltechAUTHORS:20161128-075820774

Marinescu, Smaranda C. and Nishimata, Toyoki and Mohr, Justin T. et al. (2008) Homogeneous Pd-Catalyzed Enantioselective Decarboxylative Protonation. Organic Letters, 10 (6). pp. 1039-1042. ISSN 1523-7060. PMCID PMC2966305. https://resolver.caltech.edu/CaltechAUTHORS:20170221-162726154

Behenna, Douglas C. and Stockdill, Jennifer L. and Stoltz, Brian M. (2008) The Biology and Chemistry of the Zoanthamine Alkaloids. Angewandte Chemie International Edition, 47 (13). pp. 2365-2386. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20170215-151808188

Gilmore, Christopher D. and Allan, Kevin M. and Stoltz, Brian M. (2008) Orthogonal Synthesis of Indolines and Isoquinolines via Aryne Annulation. Journal of the American Chemical Society, 130 (5). pp. 1558-1559. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170223-153451419

White, David E. and Stewart, Ian C. and Grubbs, Robert H. et al. (2008) The Catalytic Asymmetric Total Synthesis of Elatol. Journal of the American Chemical Society, 130 (3). pp. 810-811. ISSN 0002-7863. PMCID PMC2533138. https://resolver.caltech.edu/CaltechAUTHORS:20170222-082042531

Nelson, Hosea M. and Stoltz, Brian M. (2008) Progress toward the Synthesis of the Basiliolides and Transtaganolides: An Intramolecular Pyrone Diels−Alder Entry into a Novel Class of Natural Products. Organic Letters, 10 (1). pp. 25-28. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20170222-094911569

2007

Mohr, Justin T. and Stoltz, Brian M. (2007) Enantioselective Tsuji Allylations. Chemistry – An Asian Journal, 2 (12). pp. 1476-1491. ISSN 1861-4728. PMCID PMC2967289. https://resolver.caltech.edu/CaltechAUTHORS:20170215-130857215

Mohr, Justin T. and Ebner, David C. and Stoltz, Brian M. (2007) Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis. Organic and Biomolecular Chemistry, 5 (22). pp. 3571-3576. ISSN 1477-0520. PMCID PMC2963431. https://resolver.caltech.edu/CaltechAUTHORS:20170223-071515692

Keith, John A. and Behenna, Douglas C. and Mohr, Justin T. et al. (2007) The Inner-Sphere Process in the Enantioselective Tsuji Allylation Reaction with (S)-t-Bu-phosphinooxazoline Ligands. Journal of the American Chemical Society, 129 (39). pp. 11876-11877. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170222-080249889

Liu, Qi and Ferreira, Eric M. and Stoltz, Brian M. (2007) Convergency and Divergency as Strategic Elements in Total Synthesis: The Total Synthesis of (−)-Drupacine and the Formal Total Synthesis of (±)-Cephalotaxine, (−)-Cephalotaxine, and (+)-Cephalotaxine. Journal of Organic Chemistry, 72 (19). pp. 7352-7358. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20170215-155814896

Tani, Kousuke and Behenna, Douglas C. and McFadden, Ryan M. et al. (2007) A Facile and Modular Synthesis of Phosphinooxazoline Ligands. Organic Letters, 9 (13). pp. 2529-2531. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20170222-151224179

Behenna, Douglas C. and Stockdill, Jennifer L. and Stoltz, Brian M. (2007) Synthesis of the Carbocyclic Core of Zoanthenol: Implementation of an Unusual Acid-Catalyzed Cyclization. Angewandte Chemie International Edition, 46 (22). pp. 4077-4080. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20170215-152142036

Ly, Tony and Krout, Michael and Pham, Don K. et al. (2007) Synthesis of 2-Quinuclidonium by Eliminating Water: Experimental Quantification of the High Basicity of Extremely Twisted Amides. Journal of the American Chemical Society, 129 (7). pp. 1864-1865. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170222-084852047

2006

Ferreira, Eric M. and Stoltz, Brian M. (2006) The synthesis of C-3β functionalized indoles via a hydroboration/Suzuki–Miyaura coupling sequence. Tetrahedron Letters, 47 (48). pp. 8579-8582. ISSN 0040-4039. PMCID PMC1832155. https://resolver.caltech.edu/CaltechAUTHORS:20161128-080903512

Tambar, Uttam K. and Kano, Taichi and Zepernick, John F. et al. (2006) Convergent and Diastereoselective Synthesis of the Polycyclic Pyran Core of Saudin. Journal of Organic Chemistry, 71 (22). pp. 8357-8364. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20170223-142410037

Garg, Neil K. and Stoltz, Brian M. (2006) A unified synthetic approach to the pyrazinone dragmacidins. Chemical Communications, 2006 (36). pp. 3769-3779. ISSN 1359-7345. https://resolver.caltech.edu/CaltechAUTHORS:GARcc06

Tambar, Uttam K. and Ebner, David C. and Stoltz, Brian M. (2006) A Convergent and Enantioselective Synthesis of (+)-Amurensinine via Selective C−H and C−C Bond Insertion Reactions. Journal of the American Chemical Society, 128 (36). pp. 11752-11753. ISSN 0002-7863. PMCID PMC2529249. https://resolver.caltech.edu/CaltechAUTHORS:20170221-152140812

Mohr, Justin T. and Nishimata, Toyoki and Behenna, Douglas C. et al. (2006) Catalytic Enantioselective Decarboxylative Protonation. Journal of the American Chemical Society, 128 (35). pp. 11348-11349. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170222-073849342

McFadden, Ryan M. and Stoltz, Brian M. (2006) The Catalytic Enantioselective, Protecting Group-Free Total Synthesis of (+)-Dichroanone. Journal of the American Chemical Society, 128 (24). pp. 7738-7739. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170222-075015251

Tani, Kousuke and Stoltz, Brian M. (2006) Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate. Nature, 441 (7094). pp. 731-734. ISSN 0028-0836. https://resolver.caltech.edu/CaltechAUTHORS:20150319-100435030

Meyer, Michael E. and Ferreira, Eric M. and Stoltz, Brian M. (2006) 2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters. Chemical Communications, 2006 (12). pp. 1316-1318. ISSN 1359-7345. https://resolver.caltech.edu/CaltechAUTHORS:MEYcc06

Lacenere, Christopher J. and Garg, Neil K. and Stoltz, Brian M. et al. (2006) Effects of a Modified Dye-Labeled Nucleotide Spacer Arm on Incorporation by Thermophilic DNA Polymerases. Nucleosides, Nucleotides and Nucleic Acids, 25 (1). pp. 9-15. ISSN 1525-7770. https://resolver.caltech.edu/CaltechAUTHORS:20170223-112338543

2005

Trend, Raissa M. and Ramtohul, Yeeman K. and Stoltz, Brian M. (2005) Oxidative Cyclizations in a Nonpolar Solvent Using Molecular Oxygen and Studies on the Stereochemistry of Oxypalladation. Journal of the American Chemical Society, 127 (50). pp. 17778-17788. ISSN 0002-7863. PMCID PMC2585987. https://resolver.caltech.edu/CaltechAUTHORS:20170216-152155230

Mohr, Justin T. and Behenna, Douglas C. and Harned, Andrew M. et al. (2005) Deracemization of Quaternary Stereocenters by Pd-Catalyzed Enantioconvergent Decarboxylative Allylation of Racemic β-Ketoesters. Angewandte Chemie International Edition, 44 (42). pp. 6924-6927. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20170215-153759053

Caspi, Daniel D. and Garg, Neil K. and Stoltz, Brian M. (2005) Heterogeneous Reductive Isomerization Reaction Using Catalytic Pd/C and H_2. Organic Letters, 7 (12). pp. 2513-2516. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20170222-150113004

Tambar, Uttam K. and Kano, Taichi and Stoltz, Brian M. (2005) Progress toward the Total Synthesis of Saudin: Development of a Tandem Stille-Oxa-Electrocyclization Reaction. Organic Letters, 7 (12). pp. 2413-2416. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20170222-144318676

Garg, Neil K. and Caspi, Daniel D. and Stoltz, Brian M. (2005) Development of an Enantiodivergent Strategy for the Total Synthesis of (+)- and (−)-Dragmacidin F from a Single Enantiomer of Quinic Acid. Journal of the American Chemical Society, 127 (16). pp. 5970-5978. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170222-093427303

Tambar, Uttam K. and Stoltz, Brian M. (2005) The Direct Acyl-Alkylation of Arynes. Journal of the American Chemical Society, 127 (15). pp. 5340-5341. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170222-085357234

Garg, Neil K. and Woodroofe, Carolyn C. and Lacenere, Christopher J. et al. (2005) A ligand-free solid-supported system for Sonogashira couplings: applications in nucleoside chemistry. Chemical Communications, 2005 (36). pp. 4551-4553. ISSN 1359-7345. https://resolver.caltech.edu/CaltechAUTHORS:GARcc05

2004

Behenna, Douglas C. and Stoltz, Brian M. (2004) The Enantioselective Tsuji Allylation. Journal of the American Chemical Society, 126 (46). pp. 15044-15045. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170215-141008792

Behenna, Douglas C. and Stoltz, Brian M. (2004) The Enantioselective Tsuji Allylation. Journal of the American Chemical Society, 126 (46). pp. 15044-15045. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170420-084322708

Zhang, Haiming and Ferreira, Eric M. and Stoltz, Brian M. (2004) Direct Oxidative Heck Cyclizations: Intramolecular Fujiwara-Moritani Arylations for the Synthesis of Functionalized Benzofurans and Dihydrobenzofurans. Angewandte Chemie International Edition, 43 (45). pp. 6144-6148. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20170221-114810808

Garg, Neil K. and Caspi, Daniel D. and Stoltz, Brian M. (2004) The Total Synthesis of (+)-Dragmacidin F. Journal of the American Chemical Society, 126 (31). pp. 9552-9553. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170215-153256032

Nielsen, Robert J. and Keith, Jason M. and Stoltz, Brian M. et al. (2004) A Computational Model Relating Structure and Reactivity in Enantioselective Oxidations of Secondary Alcohols by (−)-Sparteine−Pd^(II) Complexes. Journal of the American Chemical Society, 126 (25). pp. 7967-7974. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170215-152829202

Trend, Raissa M. and Stoltz, Brian M. (2004) An Experimentally Derived Model for Stereoselectivity in the Aerobic Oxidative Kinetic Resolution of Secondary Alcohols by (Sparteine)PdCl_2. Journal of the American Chemical Society, 126 (14). pp. 4482-4483. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170216-072248452

Su, Julius T. and Sarpong, Richmond and Stoltz, Brian M. et al. (2004) Substituent Effects and Nearly Degenerate Transition States: Rational Design of Substrates for the Tandem Wolff−Cope Reaction. Journal of the American Chemical Society, 126 (1). pp. 24-25. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170216-074904738

Bagdanoff, Jeffrey T. and Stoltz, Brian M. (2004) Palladium-Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation Gas. Angewandte Chemie International Edition, 43 (3). pp. 353-357. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20170215-145714988

2003

Ashley, Eric R. and Cruz, Ernest G. and Stoltz, Brian M. (2003) The Total Synthesis of (−)-Lemonomycin. Journal of the American Chemical Society, 125 (49). pp. 15000-15001. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170216-075818295

Sarpong, Richmond and Su, Julius T. and Stoltz, Brian M. (2003) The Development of a Facile Tandem Wolff/Cope Rearrangement for the Synthesis of Fused Carbocyclic Skeletons. Journal of the American Chemical Society, 125 (45). pp. 13624-13625. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170215-143652773

Ferreira, Eric M. and Stoltz, Brian M. (2003) Catalytic C−H Bond Functionalization with Palladium(II): Aerobic Oxidative Annulations of Indoles. Journal of the American Chemical Society, 125 (32). pp. 9578-9579. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170216-082726177

Trend, Raissa M. and Ramtohul, Yeeman K. and Ferreira, Eric M. et al. (2003) Palladium-Catalyzed Oxidative Wacker Cyclizations in Nonpolar Organic Solvents with Molecular Oxygen: A Stepping Stone to Asymmetric Aerobic Cyclizations. Angewandte Chemie International Edition, 42 (25). pp. 2892-2895. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20170221-131404095

Julian, Ryan R. and May, Jeremy A. and Stoltz, Brian M. et al. (2003) Gas-Phase Synthesis of Charged Copper and Silver Fischer Carbenes from Diazomalonates: Mechanistic and Conformational Considerations in Metal-Mediated Wolff Rearrangements. Journal of the American Chemical Society, 125 (15). pp. 4478-4486. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170215-152031857

Bagdanoff, Jeffrey T. and Ferreira, Eric M. and Stoltz, Brian M. (2003) Palladium-Catalyzed Enantioselective Oxidation of Alcohols: A Dramatic Rate Acceleration by Cs_2CO_3/t-BuOH. Organic Letters, 5 (6). pp. 835-837. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20170222-145100100

Julian, Ryan R. and May, Jeremy A. and Stoltz, Brian M. et al. (2003) Molecular Mousetraps: Gas-Phase Studies of the Covalent Coupling of Noncovalent Complexes Initiated by Reactive Carbenes Formed by Controlled Activation of Diazo Precursors. Angewandte Chemie International Edition, 42 (9). pp. 1012-1015. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20170223-161950902

2002

Garg, Neil K. and Sarpong, Richmond and Stoltz, Brian M. (2002) The First Total Synthesis of Dragmacidin D. Journal of the American Chemical Society, 124 (44). pp. 13179-13184. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170215-142231422

May, Jeremy A. and Stoltz, Brian M. (2002) Non-Carbonyl-Stabilized Metallocarbenoids in Synthesis: The Development of a Tandem Rhodium-Catalyzed Bamford−Stevens/Thermal Aliphatic Claisen Rearrangement Sequence. Journal of the American Chemical Society, 124 (42). pp. 12426-12427. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170215-150235551

Spessard, Sarah J. and Stoltz, Brian M. (2002) Progress toward the Synthesis of Garsubellin A and Related Phloroglucins: The Direct Diastereoselective Synthesis of the Bicyclo[3.3.1]nonane Core. Organic Letters, 4 (11). pp. 1943-1946. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20170215-135249615

2001

Ferreira, Eric M. and Stoltz, Brian M. (2001) The Palladium-Catalyzed Oxidative Kinetic Resolution of Secondary Alcohols with Molecular Oxygen. Journal of the American Chemical Society, 123 (31). pp. 7725-7726. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170215-134639074

2000

Fuerst, Douglas E. and Stoltz, Brian M. and Wood, John L. (2000) Synthesis of C(3) Benzofuran-Derived Bisaryl Quaternary Centers: Approaches to Diazonamide A. Organic Letters, 2 (22). pp. 3521-3523. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20170215-134104826

Ge, Min and Stoltz, Brian M. and Corey, E. J. (2000) Mechanistic Insights into the Factors Determining Exo−EndoSelectivity in the Lewis Acid-Catalyzed Diels−Alder Reaction of 1,3-Dienes with 2-Cycloalkenones. Organic Letters, 2 (13). pp. 1927-1929. ISSN 1523-7060. https://resolver.caltech.edu/CaltechAUTHORS:20170222-101505337

This list was generated on Sun May 16 22:08:12 2021 PDT.