The synthesis of some intermediates for use in the preparation of analogs of salicylaldehyde ethylenediimine cobalt (salcomine)
Abstract
As part of a study having for its object the examination of the oxygen-carrying properties of chelate compounds of the type exemplified by salicylaldehyde ethylenediimine cobalt ("Salcomine") (I) a large number of substances were prepared and tested in an effort to determine the structural requirements for activity and to discover chelates with oxygen-carrying properties superior to those of I. Among the practical improvements sought were (a) greater stability than Salcomine in repeated passage through the cycle of oxygenation and deoxygenation; (b) greater oxygen capacity (over the capacity of one atom of oxygen per mole of chelate possessed by Salcomine); and (e) increased rates of oxygenation and deoxygenation under conveniently attainable temperature and pressure conditions.
Additional Information
© 1946 American Chemical Society. The work described in this paper was carried out as part of a program of research under Division 11, Section 1, of the National Defense Research Committee, under a contract between the Office of Scientific Research and Development and the University of California.Additional details
- Eprint ID
- 60625
- DOI
- 10.1021/jo01176a015
- Resolver ID
- CaltechAUTHORS:20150930-135821351
- National Defense Research Committee
- Created
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2015-10-13Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field