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Published June 21, 2013 | Published
Journal Article Open

Rational design of p-type thermoelectric PbTe: temperature dependent sodium solubility

Abstract

We develop a solid understanding of the temperature-dependent solubility of sodium in p-type PbTe, the most efficient thermoelectric material. The maximum solubility of sodium telluride (NaTe) in PbTe is measured to be 1.4 ± 0.3 at% and the heat of solution is evaluated as 26^(+19)_(−11) kJ mol^(−1) that addresses fundamental issues regarding the formation of nano-precipitates.

Additional Information

© 2013 The Royal Society of Chemistry. Received 26th April 2013; Accepted 20th June 2013. First published online 21 Jun 2013. This work is supported by the BaoSteel Australia R&D Centre, the Department of Education, Science and Technology (DEST) of Australia, ARC Discovery Early Career Award DE130100310 and the NASA Jet Propulsion Laboratory.

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