Published April 9, 2007
| Version Supplemental Material
Journal Article
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Synthesis of N-Heterocylic Carbene-Containing Metal Complexes from 2-(Pentafluorophenyl)imidazolidines
Abstract
N-Heterocyclic carbene (NHC)-containing metal complexes are prepared through a simple, base-free method involving the decomposition of 2-(pentafluorophenyl)imidazolidines under mild thermolytic conditions. Ruthenium, iridium, and rhodium complexes containing NHC ligands with different electronic and steric parameters are reported.
Additional Information
© 2007 American Chemical Society. Received 14 October 2006. Published online 6 March 2007. Published in print 1 April 2007. T.R. thanks the German Academic Exchange Service (DAAD) for a postdoctoral fellowship. The authors thank Irina Gorodetskaya, Dr. Anna G. Wenzel, and Dr. Georgios C. Vougioukalakis for starting materials. Dr. Michael W. Day and Lawrence M. Henling are thanked for crystallographic work.Attached Files
Supplemental Material - om060949fsi20061012_060716.cif
Supplemental Material - om060949fsi20070106_023627.pdf
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Additional details
Identifiers
- Eprint ID
- 79337
- DOI
- 10.1021/om060949f
- Resolver ID
- CaltechAUTHORS:20170725-111928004
Funding
- Deutscher Akademischer Austauschdienst (DAAD)
Dates
- Created
-
2017-07-25Created from EPrint's datestamp field
- Updated
-
2021-11-15Created from EPrint's last_modified field