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Published October 16, 2023 | Published
Journal Article Open

Soluble organic matter Molecular atlas of Ryugu reveals cold hydrothermalism on C-type asteroid parent body

Abstract

The sample from the near-Earth carbonaceous asteroid (162173) Ryugu is analyzed in the context of carbonaceous meteorites soluble organic matter. The analysis of soluble molecules of samples collected by the Hayabusa2 spacecraft shines light on an extremely high molecular diversity on the C-type asteroid. Sequential solvent extracts of increasing polarity of Ryugu samples are analyzed using mass spectrometry with complementary ionization methods and structural information confirmed by nuclear magnetic resonance spectroscopy. Here we show a continuum in the molecular size and polarity, and no organomagnesium molecules are detected, reflecting a low temperature and water-rich environment on the parent body approving earlier mineralogical and chemical data. High abundance of sulfidic and nitrogen rich compounds as well as high abundance of ammonium ions confirm the water processing. Polycyclic aromatic hydrocarbons are also detected in a structural continuum of carbon saturations and oxidations, implying multiple origins of the observed organic complexity, thus involving generic processes such as earlier carbonization and serpentinization with successive low temperature aqueous alteration.

Copyright and License

© The Author(s) 2023. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Acknowledgement

The Hayabusa2 project has been led by JAXA (Japan Aerospace Exploration Agency) in collaboration with DLR (German Space Center) and CNES (French Space Center), and supported by NASA and ASA (Australian Space Agency). We thank all of the members of the Hayabusa2 project for their technical and scientific contributions. We thank Dr. Laurence Garvie from ASU (Arizona State University) and the Buseck Center Meteorite Studies for some selected fragments of meteorites used in this study. This research is partly supported by the Japan Society for the Promotion of Science (JSPS) under KAKENHI grant numbers JP20H00202, JP20H05846, JP20K20485, JP20K14549, JP21J00504, JP21H01203, JP21H04501, and JP21KK0062. J.P.D., J.C.A., E.T.P., D.P.G., H.L.M., J.E.E., and H.V.G. are grateful to NASA for support of the Consortium for Hayabusa2 Analysis of Organic Solubles. This research is also funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – Project-ID 364653263 – TRR 235 (CRC 235).

Funding

Open Access funding enabled and organized by Projekt DEAL.

Additional Information

Consortia

Hayabusa2-initial-analysis SOM team

  • Philippe Schmitt-Kopplin
  • , Norbert Hertkorn
  • , Hiroshi Naraoka
  • , Yoshinori Takano
  • , Jason P. Dworkin
  • , Kenji Hamase
  • , Aogu Furusho
  • , Minako Hashiguchi
  • , Kazuhiko Fukushima
  • , Dan Aoki
  • , José C. Aponte
  • , Eric T. Parker
  • , Daniel P. Glavin
  • , Hannah L. McLain
  • , Jamie E. Elsila
  • , Heather V. Graham
  • , John M. Eiler
  • , Alexander Ruf
  • , Francois-Regis Orthous-Daunay
  • , Junko Isa
  • , Véronique Vuitton
  • , Roland Thissen
  • , Nanako O. Ogawa
  • , Saburo Sakai
  • , Toshihiro Yoshimura
  • , Toshiki Koga
  • , Haruna Sugahara
  • , Naohiko Ohkouchi
  • , Hajime Mita
  • , Yoshihiro Furukawa
  • , Yasuhiro Oba
  • & Shogo Tachibana

Contributions

P.S.-K. designed this research. P.S.-K. and N.H. conducted experiments and analyzed data in cooperation with M.H., M.L., F.M., L.B., and E.Q. P.S.-K. wrote the paper. S.T., H. Yurimoto, T. Nakamura, T. Noguchi, R.O., H. Yabuta, and H.N. administered the initial analysis with J.D., Y. Takano, and M.A. T. Yada, M.N., K.Y., A.N., M.Y., A.M., and T.U. curated samples. K.S., T.O., S.N., F.T., S. Tanaka, and T.S. contributed to science operations of the spacecraft. S.-i.W. and Y. Tsuda administered the project. All authors discussed the results and commented on the manuscript.

Data Availability

All data from the mission are available at the DARTS archive www.darts.isas.jaxa.jp/planet/project/hayabusa2/ and on the Small Bodies Node of the NASA Planetary Data System https://pds-smallbodies.astro.umd.edu/data_sb/missions/hayabusa2/. The samples of Ryugu are curated by the JAXA Astromaterials Science Research Group; distribution for analysis is through an Announcement of Opportunity available at https://jaxa-ryugu-sample-ao.net. The FTICR-MS raw data can be make available in contacting the corresponding author and can be adapted depending on further utilization.

Conflict of Interest

The authors declare no competing interests.

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Additional details

Created:
October 17, 2023
Modified:
October 17, 2023