Published 2005 | Version Published + Supplemental Material
Journal Article Open

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as –0.28 V vs. SCE.

Additional Information

© Royal Society of Chemistry 2005 Received (in Berkeley, CA, USA) 28th June 2005, Accepted 29th July 2005. First published on the web 23rd August 2005 For financial support we acknowledge the NSF through a Chemical Bonding Center (CBC). We also thank Prof. Alex Sessions for his generous help with the gas chromatography experiments.

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Additional details

Identifiers

Eprint ID
4825
Resolver ID
CaltechAUTHORS:HUXcc05

Funding

NSF

Dates

Created
2006-09-08
Created from EPrint's datestamp field
Updated
2021-11-08
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