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Published December 27, 2000 | Supplemental Material
Journal Article Open

Tandem Catalysis: Three Mechanistically Distinct Reactions from a Single Ruthenium Complex


Organometallic catalysts are traditionally designed and optimized to mediate a single reaction. As the number of applications that require combinatorial and other high-speed synthetic protocols increases, it will become desirable for catalysts to mediate multiple, mechanistically distinct transformations directly or upon simple modification. As an example of such a system, we demonstrate the ability of a single component precatalyst to mediate three different reactions to form well-defined block copolymers.

Additional Information

© 2000 American Chemical Society. Received 17 May 2000. Published online 5 December 2000. Published in print 1 December 2000. C.B. is grateful to the National Science Foundation for a predoctoral fellowship. J.L. is grateful to the National Institute of Health for a postdoctoral fellowship.

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Supplemental Material - ja001698j_s.pdf


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