Published March 1977
| public
Journal Article
The Very low-pressure pyrolysis of 2-phenylethylamine. The enthalpy of formation of the aminomethyl radical
- Creators
-
Colussi, A. J.
- Benson, S. W.
Abstract
The thermal unimolecular decomposition of 2-phenylethylamine (PhCH2CH2NH2) into benzyl and aminomethyl radicals has been studied under very-low-pressure conditions, and the enthalpy of formation of the aminomethyl radicals, ΔH^°_f, 298K (H_2NCH_2^·) = 37.0 ± 2.0 kcal/mol, has been derived from the kinetic data. This result leads to a value for the C—H bond dissociation energy in methylamine, BDE(H_2NCH_2—H) = 94.6 ± 2.0 kcal/mol, which is about 3.4 kcal/mol lower than in C_2H_6 (98 kcal/mol), indicating a sizable stabilization in α-aminoalkyl radicals.
Additional Information
© 1977 John Wiley & Sons. Received July 8, 1976; Revised September 22, 1976. This work was supported in part by the National Science Foundation under Grant MPS 74-18565 and by the Environmental Protection Agency under Grant R 802288.Additional details
- Eprint ID
- 59103
- Resolver ID
- CaltechAUTHORS:20150731-095056608
- NSF
- MPS 74-18565
- Environmental Protection Agency (EPA)
- R 802288
- Created
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2015-08-06Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field