CaltechAUTHORS
Published August 10, 2011 | Version Published + Supplemental Material
Journal Article Open

Iridium complexes bearing a PNP ligand, favoring facile C(sp^3)–H bond cleavage

Creators

  • 1. ROR icon Scripps Research Institute
  • 2. ROR icon California Institute of Technology
  • 3. ROR icon The University of Texas at Arlington

Abstract

Hydrogen iodide is lost upon reaction of PNP with IrI_3, where PNP = 2,6-bis-(di-t-butylphosphinomethyl)pyridine to give crystallographically characterized Ir(PNP)*(I)_2, which reacts with H_2 to give Ir(PNP)(H)(I)_2. Ir(PNP)(Cl)_3 is relatively inert towards the intramolecular C–H activation of the tert-butyl's of the PNP ligand.

Additional Information

© 2011 The Royal Society of Chemistry. Received 4th April 2011. Accepted 6th July 2011. First published on the web 10th August 2011. This material is based upon work supported by Chevron Energy Technology Company, by the Center for Catalytic Hydrocarbon Functionalization, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DOE DE-SC000-1298 and by Scripps Florida.

Attached Files

Published - Lokare2011p15829Dalton_Transactions.pdf

Supplemental Material - c1dt10577a.pdf

Supplemental Material - c1dt10577a.txt

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c1dt10577a.pdf

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Additional details

Identifiers

Eprint ID
25415
Resolver ID
CaltechAUTHORS:20110922-155211533

Funding

Chevron Energy Technology Company
Department of Energy (DOE)
DE-SC000-1298
Scripps Florida

Dates

Created
2011-09-23
Created from EPrint's datestamp field
Updated
2021-11-09
Created from EPrint's last_modified field