Published June 30, 2024 | Published
Journal Article Open

Multiple-year battery based on highly efficient and stable dual-site radioactive isotope dye-sensitized betavoltaic cell

Abstract

There is an unmet need for a battery that can provide full power for several decades for applications powering implants, remote applications, and satellites. We develop a novel betavoltaic device, a dual-site radioactive isotope dye-sensitized betavoltaic cell (d-DSBC), which is powered by the decay energy of the radioactive isotope of carbon. This device treats both the anode and cathode with a β-radiation source (dual-site source) to achieve a betavoltaic design with improved β-radiation absorption. The anode is composed of a TiO2 layer first coated with radioactive isotope of citric acid, and then a ruthenium complex dye that acts as a charge generating layer. The cathode consists of a radioactive isotope of carbon nanoparticles/quantum dots. The d-DSBC exhibits a high power density per radioactive source of 20.75 nW cm−2 mCi−1, and an energy conversion efficiency of 2.86 %. These results represent a considerable step towards the practical application of betavoltaic cells.

Copyright and License

© 2024 Elsevier.

Acknowledgement

The authors gratefully acknowledge the support of the National Research Foundation of Korea (NRF) (2021R1A2C2009459 and 5199991614244 (BK21 FOUR)), and Dae Han environmental Industry Co., Ltd.

Contributions

Hong Soo Kim: Writing – review & editing, Writing – original draft, Software, Methodology, Investigation, Formal analysis, Data curation, Conceptualization. Junho Lee: Writing – original draft, Software, Methodology, Investigation, Formal analysis, Data curation. Sanghun Lee: Methodology, Formal analysis, Data curation. Niket S. Powar: Writing – review & editing, Writing – original draft. Muhammad Bilal Naseem: Writing – review & editing, Writing – original draft. Chol Hyun Kim: Writing – original draft, Writing – original draft. Haoran Zhou: Writing – review & editing, Writing – original draft. Hwan Kyu Kim: Writing – review & editing, Writing – original draft. William A. Goddard: Writing – review & editing, Validation. Su-Il In: Writing – review & editing, Writing – original draft, Validation, Supervision, Resources, Funding acquisition, Conceptualization.

Data Availability

Appendix A. Supplementary data

Conflict of Interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

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Additional details

Created:
May 30, 2024
Modified:
May 30, 2024