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Published December 3, 2013 | Published
Journal Article Open

Reprint of: Femtosecond transition-state spectroscopy of iodine: From strongly bound to repulsive surface dynamics

Abstract

The application of femtosecond transition-state spectroscopy (FTS) to molecular iodine is reported. The real-time motion of wave packets prepared coherently in the bound B state is observed. In addition, the motion is probed near and above the dissociation limit for the reaction: I_2 → I (^2P_(3/2)) + I∗(^2P_(1/2)). FTS measurements of the dynamics on repulsive surfaces are also reported.

Additional Information

© 2013 Published by Elsevier B.V. An Open Access article. Available online 21 August 2013. This work was supported by a grant from the Air Force Office of Scientific Research.

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