Published August 13, 2012
| Supplemental Material
Journal Article
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A Versatile Ligand Platform that Supports Lewis Acid Promoted Migratory Insertion
Abstract
A helping hand: Incorporation of Group 2 Lewis acids into a macrocycle appended to a phosphine ligand attached to a rhenium carbonyl complex promotes otherwise unfavorable transformations of coordinated CO (see scheme; M=Ca, Sr). These Lewis acids form relatively weak M-O bonds, thereby enabling release of organic products from the metal center.
Additional Information
© 2012 Wiley-VCH Verlag. Received: April 27, 2012. Published online: July 6, 2012. This work was supported by BP through the XC2 program. We thank Larry Henling and Michael Day for assistance with crystallography.Attached Files
Supplemental Material - anie_201203264_sm_miscellaneous_information.pdf
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anie_201203264_sm_miscellaneous_information.pdf
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Additional details
- Eprint ID
- 34354
- DOI
- 10.1002/anie.201203264
- Resolver ID
- CaltechAUTHORS:20120925-115241978
- BP XC2 Program
- Created
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2012-09-25Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field