Published March 26, 2007
| Version Supplemental Material
Journal Article
Open
Mechanistic Analysis of Iridium Heteroatom C−H Activation: Evidence for an Internal Electrophilic Substitution Mechanism
Creators
-
1.
California Institute of Technology
-
2.
University of Southern California
Abstract
The mechanism responsible for C−H activation in Ir(acac)_2(OCH_3)(C_6H_6) has been identified and described as an internal electrophilic substitution (IES) mechanism, on the basis of orbital changes and predicted reactivity. In this IES mechanism, the lone pair on a M−X ligand forms an X−H bond, while the orbital making up the M−X bond turns into a coordinating lone pair.
Additional Information
© 2007 American Chemical Society. Received 29 December 2006. Published online 23 February 2007. Published in print 1 March 2007. We thank Chevron Energy Technology Co., the National Science Foundation (Grant No. CHE-0328121), and the ONR (Grant No. MURI-N00014-02-1-0665) for financial support.Attached Files
Supplemental Material - om061189bsi20061229_022559.pdf
Files
om061189bsi20061229_022559.pdf
Files
(80.7 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:5b02ae765e66ade932c0cb9f92f04905
|
80.7 kB | Preview Download |
Additional details
Identifiers
- Eprint ID
- 79335
- DOI
- 10.1021/om061189b
- Resolver ID
- CaltechAUTHORS:20170725-110427930
Funding
- Chevron Energy Technology Co.
- NSF
- CHE-0328121
- Office of Naval Research (ONR)
- N00014-02-1-0665
Dates
- Created
-
2017-07-25Created from EPrint's datestamp field
- Updated
-
2021-11-15Created from EPrint's last_modified field