Accelerated screening of carbon dioxide capture by liquid sorbents
Abstract
The ideation of carbon capture, concentration, and utilization technologies is establishing a need for carbon dioxide sorbents with specific binding, release, and chemical specifications. While computational workflows can help navigate the broad search space of molecular sorbents, automated experimental screening platforms are relatively underdeveloped. We present a carbon capture screening instrument to characterize the carbon dioxide binding and sorption capacity of liquid sorbent media. We discuss the extension of this capability to characterize the loaded liquid sorbent as well as the headspace to facilitate study of the carbon dioxide adduct, for example its electrochemical activation. The fabrication and computer automation instructions are provided so that the experimental technique can be implemented in a broad range of materials acceleration platforms involving gas sorption.
Contributions
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Acknowledgement
This material is based upon work performed by the Center for Closing the Carbon Cycle, which is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences Energy Frontier Research Centers program under Award Number DE-SC0023427.
Contributions
R. J. J. and J. M. G. designed the CCSI with input from J. Y. Y., A. M. A., and J. A. H. R. J. J. and K. K. assembled and validated the CCSI. R. J. R., K. K., and D. G. developed the instrument control software with validation experiments by K. K. and Y. L. Y. L. operated CCSI and analyzed its data. C. L. and N. M. R. synthesized and characterized the phenoxide sorbent under supervision of J. Y. Y. J. M. G. was the primary author of the manuscript with contributions from all authors. R. J. R, K. K., and Y. L. were the primary authors of the assembly and operation instructions.
Data Availability
The instrument control software is available at https://github.com/High-Throughput-Experimentation/helao-async, with dependencies in https://github.com/High-Throughput-Experimentation/helao-core. The computer drawings of the instrument, instrumentation control software (helao snapshot), the data files acquired for the present work, and the source code for the analysis and plotting of those data are provided via CaltechData at https://data.caltech.edu/records/5z5zz-m9r81 (doi: 10.22002/5z5zz-m9r81). The license for the CCSI hardware is included alongside the design files in that repository, as well as a ESI document† for this manuscript.
Conflict of Interest
A patent application for the CCSI has been filed. J. M. G. is an industrial consultant for experiment automation.
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Additional details
- United States Department of Energy
- DE-SC0023427