Published November 21, 2024 | Published
Journal Article Open

Insights of the peroxychloroformyl radical ClC(O)OO via microwave spectrum

  • 1. ROR icon National Chiao Tung University
  • 2. ROR icon California Institute of Technology
  • 3. ROR icon Jet Propulsion Lab

Abstract

Pure rotational spectra of trans-ClC(O)O2 (left) and cis-ClC(O)O2 (right), and the potential energy curve connecting the two conformers. The energy diagram and the observed transitions for the trans-ClC(O)O2 are also shown.

Copyright and License

© the Owner Societies 2024

Acknowledgement

The research was supported by the National Science and Technology Council of Taiwan (grants MOST108-2113-M-009-025, MOST109-2113-M-009-024). The work of WC and FW was supported in part by Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (80NM0018D0004). The authors thank Prof. Yuan-Pern Lee for sharing necessary lab supplies.

Data Availability

All the date in the manuscript is included in the ESI.

Contributions

Ching-Hua Chang: data curation, formal analysis, investigation, writing – review & editing. Wen Chao: conceptualization. Cheng-Hua Tsai: formal analysis, investigation. Mitchio Okumura: conceptualization, writing – review. Frank A. F. Winiberg: conceptualization, writing – review. Yasuki Endo: conceptualization, data curation, formal analysis, funding acquisition, methodology, software, writing – review & editing.

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Additional details

Created:
December 7, 2024
Modified:
December 7, 2024