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Published July 15, 1987 | Published
Journal Article Open

Real-time picosecond clocking of the collision complex in a bimolecular reaction: The birth of OH from H+CO_2

Abstract

Picosecond (and femtosecond) photofragment spectroscopy has recently provided time-resolved, state-to-state dynamics of molecular photofragmentation. The focus of these experiments was on unimolecular reactions, where two main issues are fundamental to the dynamics: the nature of the "half-collision" and the degree to which statistical theories account for the time evolution of product state distributions (PSDs).

Additional Information

© 1987 American Institute of Physics. Received 13 April 1987; accepted 12 May 1987. Research supported by the National Science Foundation under Grant No. DMR-8521191.

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