Published January 15, 1988
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Journal Article
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Picosecond IVR dynamics of p-difluorobenzene and p-fluorotoluene in a molecular beam: Comparison with chemical timing data
Abstract
We present in this Communication preliminary time-resolved fluorescence measurements of supersonaically cooled samples of pDFB and pFT. These measurements indicate that IVR in both cold molecules up to ~1600 cm^-1 of excess vibrational energy is substantially less than that reported for the same vibrational excitations in room temperature chemical timing studies.
Additional Information
© 1988 American Institute of Physics. Received 1 October 1987; accepted 3 November 1987. This research was supported by Grant No. CHE-8512887 from the National Science Foundation. [A.H.Z. was a] John Simon Guggenheim Foundation Fellow. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 7660.Attached Files
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Additional details
Identifiers
- Eprint ID
- 11742
- Resolver ID
- CaltechAUTHORS:BASjcp88
Funding
- NSF
- CHE-8512887
- John Simon Guggenheim Foundation
Dates
- Created
-
2008-09-22Created from EPrint's datestamp field
- Updated
-
2021-11-08Created from EPrint's last_modified field
Caltech Custom Metadata
- Other Numbering System Name
- Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 7660