Remote sensing of atmospheric HDO/H₂O in southern California from CLARS-FTS

Atmospheric isotopologues of water vapor (e.g., HDO) are important tracers for understanding Earth's hydrological cycles. Most remote sensing and in-situ measurements of these isotopologues, however, are either column averaged values or sparse in space and time. Measurements targeting the planetary boundary layer (PBL), the part of the atmosphere that has high sensitivity to surface sources of water vapor isotopologues, are much rarer. In this study, we retrieved HDO and H₂O columns from observations by the California Laboratory for Atmospheric Remote Sensing Fourier Transform Spectrometer (CLARS-FTS), a mountaintop observatory on Mt. Wilson (1.67 km a.s.l.) overlooking the Los Angeles (LA) basin in southern California. CLARS-FTS observations are highly sensitive to the lower atmosphere due to the long light path along the PBL. Retrievals were conducted using spectral windows between 6000 and 7000 cm⁻¹ from CLARS-FTS observations (2011–2019). The isotopological abundance δ_D, which represents the relative difference of the HDO/H₂O ratio to a standard abundance ratio, is also calculated. The averaged δ_D retrievals are (−156.1 ± 60.0)‰ with an uncertainty of (6.1 ± 10.2)‰ for LA Basin Survey mode and (−344.7 ± 95.0)‰ with an uncertainty of (42.4 ± 31.6)‰ for Spectralon Viewing Observation mode. In LA, the δ_D shows a seasonal cycle that is primarily driven by the change of atmospheric humidity. A comparison analysis shows that the δ_D measurements by CLARS-FTS, a collocated Total Carbon Column Observing Network (TCCON), and the TROPOspheric Monitoring Instrument (TROPOMI) are in good agreement. The difference between CLARS and TCCON δ_D retrievals can primarily be attributed to the difference in their observation geometries. We envision that the HDO and δ_D measurements from CLARS-FTS provide high spatial and temporal resolution datasets for further study of hydrological processes, such as the partitioning of the water flux into soil evaporation and transpiration, standing water evaporation, or transport and mixing from the oceans, in the LA megacity.