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Published July 7, 2012 | Published + Supplemental Material
Journal Article Open

Highly regioirregular polypropylene from asymmetric group 4 anilide(pyridine)phenoxide complexes


Group 4 complexes containing an anilide(pyridine)phenoxide ligand and activated with methylaluminoxane (MAO) catalyze the formation of highly regioirregular polypropylene.

Additional Information

© 2012 The Royal Society of Chemistry. Received 19 Apr 2012, Accepted 09 May 2012. First published on the web 09 May 2012. The authors gratefully acknowledge the USDOE Office of Basic Energy Sciences (DE-FG03-85ER13431 to JEB) for funding. An NSF-GRF to RCK is gratefully acknowledged. We thank Dr Jo Ann Canich (ExxonMobil) for obtaining GPC data and Lawrence Henling and Dr Loi H. Do for help obtaining crystallographic data.

Attached Files

Published - Klet2012p18322Chem_Commun__Camb_.pdf

Supplemental Material - c2cc32806b.pdf

Supplemental Material - c2cc32806b.txt


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