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Published 1971 | Published
Journal Article Open

New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I)

Abstract

The preparation and characterization of several series of mixed ligand cobalt(I) complexes of the types [Co(CN)_2(CO)_2(PR_3)]–, [Co(CN)_2(CO)(PR_3)_2]–, and [Co(CN)(CO)_2(PR_3)_2], prepared by the reactions of tertiary phosphines (PR_3) with [Co(CN)_3(CO)_2]^(2–), are described and some novel aspects of their chemistry are discussed.

Additional Information

© 1971 Royal Society of Chemistry. Received, September 20th, 1971; Com. 1650. Support of this work by the National Science Foundation and the National Institutes of Health is gratefully acknowledged.

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August 19, 2023
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