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Published March 8, 2017 | Accepted Version
Journal Article Open

Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations


Stereoconvergent catalysis is an important subset of asymmetric synthesis that encompasses stereoablative transformations, dynamic kinetic resolutions, and dynamic kinetic asymmetric transformations. Initially, only enzymes were known to catalyze dynamic kinetic processes, but recently various synthetic catalysts have been developed. This Review summarizes major advances in nonenzymatic, transition-metal-promoted dynamic asymmetric transformations reported between 2005 and 2015.

Additional Information

© 2017 American Chemical Society. Received: October 31, 2016; Published: February 6, 2017. This work was supported in part by the NIH-NIGMS (Grant R01GM080269), Caltech, the Gordon and Betty Moore Foundation, and the Margaret E. Early Medical Research Trust. E.R.W. was supported by a Postdoctoral Fellowship, PF-16-011-01-CDD, from the American Cancer Society. The authors declare no competing financial interest.

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