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Published January 3, 2008 | Supplemental Material
Journal Article Open

Progress toward the Synthesis of the Basiliolides and Transtaganolides: An Intramolecular Pyrone Diels−Alder Entry into a Novel Class of Natural Products


Efforts directed toward the synthesis of a basiliolide/transtaganolide model system are disclosed. A highly endo-selective intramolecular pyrone Diels−Alder (IMPDA) cycloaddition rapidly constructs the tricyclic core of the basiliolides and transtaganolides.

Additional Information

© 2008 American Chemical Society. Received 12 October 2007. Published online 7 December 2007. Published in print 1 January 2008. We thank the Ford Foundation (predoctoral fellowship to H.M.N.), Abbott, Amgen, Bristol-Myers Squibb, Merck, Boehringer Ingelheim, and Caltech for generous funding.

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Supplemental Material - ol702501s-file001.pdf

Supplemental Material - ol702501s-file002.cif


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