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Published December 7, 1977 | Published
Journal Article Open

The Metallacyclopentane-Olefin Interchange Reaction


Tris(triphenylphosphine)tetramethylenenickel(II) and biscyclopentadienyltetramethylenetitanium, prepared from the reaction of a 1,4-dilithiobutane and the transition metal dihalides react with olefins to produce substituted metallacyclopentanes; the stereochemistry and substitution pattern of the metallocycles formed from propene, octa-1,7-diene, and norbornadiene has been determined.

Additional Information

© 1977 Royal Society of Chemistry. Received, 8th August 1977; Com. 829. The authors thank the National Science Foundation for support of this work.

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Published - GRUjcscc77b.pdf


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