Published December 7, 1977
| Published
Journal Article
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The Metallacyclopentane-Olefin Interchange Reaction
- Creators
-
Grubbs, Robert H.
- Miyashita, Akira
Abstract
Tris(triphenylphosphine)tetramethylenenickel(II) and biscyclopentadienyltetramethylenetitanium, prepared from the reaction of a 1,4-dilithiobutane and the transition metal dihalides react with olefins to produce substituted metallacyclopentanes; the stereochemistry and substitution pattern of the metallocycles formed from propene, octa-1,7-diene, and norbornadiene has been determined.
Additional Information
© 1977 Royal Society of Chemistry. Received, 8th August 1977; Com. 829. The authors thank the National Science Foundation for support of this work.Attached Files
Published - GRUjcscc77b.pdf
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- Eprint ID
- 32999
- Resolver ID
- CaltechAUTHORS:20120808-071724607
- NSF
- Created
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2012-08-08Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field