Nonlinearity of the post-spinel transition and its expression in slabs and plumes worldwide
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1.
Harvard University
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2.
California Institute of Technology
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3.
University of California, Los Angeles
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4.
Los Alamos National Laboratory
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Toi Ohomai Institute of Technology
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6.
University of Waikato
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7.
University of Rochester
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8.
Massachusetts Institute of Technology
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9.
Argonne National Laboratory
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10.
University of Chicago
Abstract
Phase transitions in the mantle control its internal dynamics and structure. The post-spinel transition marks the upper–lower mantle boundary, where ringwoodite dissociates into bridgmanite plus ferropericlase, and its Clapeyron slope regulates mantle flow across it. This interaction has previously been assumed to have no lateral spatial variations, based on the assumption of a linear post-spinel boundary in pressure and temperature. Here we present laser-heated diamond anvil cell experiments with synchrotron X-ray diffraction to better constrain this boundary, especially at higher temperatures. Combining our data with results from the literature, and using a global analysis based on machine learning, we find a pronounced nonlinearity in the post-spinel boundary, with its slope ranging from –4 MPa/K at 2100 K, to –2 MPa/K at 1950 K, and to 0 MPa/K at 1600 K. Changes in temperature over time and space can therefore cause the post-spinel transition to have variable effects on mantle convection and the movement of subducting slabs and upwelling plumes.
Copyright and License
© 2025, The Author(s). This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Acknowledgement
J.D. was supported by a James Mills Peirce Fellowship from the Graduate School of Arts and Sciences at Harvard University. R.F. was supported by her faculty start-up fund at Harvard University and by the Henry Luce Foundation. M.B. was supported by a National Science Foundation Graduate Research Fellowship (DGE-1745303). We thank Andrew J. Campbell for loaning us his short symmetric cell for the gas membrane experiments. The experimental part of this work was performed at GeoSoilEnviroCARS (Sector 13) and HPCAT (Sector 16), Advanced Photon Source (APS), Argonne National Laboratory. The Advanced Photon Source is a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02.06CH11357. GeoSoilEnviroCARS is supported by the National Science Foundation (EAR–1634415) and DOE (DE-FG02-94ER14466). HPCAT operations are supported by the National Nuclear Security Administration (DOE-NNSA)’s Office of Experimental Sciences. The data analysis part of this work was inspired by a Harvard class, CS109a: Introduction to Data Science, taught by Pavlos Protopapas, Kevin A. Rader, and Chris Tanner in Fall 2020, and this work benefited from its course materials.
Data Availability
The source data used to reproduce all of the figures in this study can be accessed in the Supplementary Data 1–5 and are available on Zenodo at https://doi.org/10.5281/zenodo.14188625.
Code Availability
The code used to construct the Mg2SiO4 phase diagram in this study, including detailed documentation and a benchmark case, can be accessed in the Supplementary Data 6–7, and are available on Zenodo via https://doi.org/10.5281/zenodo.14188625.
Supplemental Material
Supplementary information
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Additional details
- National Science Foundation
- EAR-1853388
- National Science Foundation
- DGE-1745303
- National Science Foundation
- EAR–1634415
- National Nuclear Security Administration
- Caltech groups
- Division of Geological and Planetary Sciences (GPS)
- Publication Status
- Published