CaltechAUTHORS
Published April 23, 2009 | Version Supplemental Material + Published
Journal Article Open

Experimental realization of catalytic CH_4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability

Creators

  • 1. ROR icon University of Southern California
  • 2. ROR icon California Institute of Technology
  • 3. ROR icon Scripps Research Institute

Abstract

A discrete, air, protic, and thermally stable (NNC)Ir(III) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO_4 and KIO_3 gives the oxy-ester.

Additional Information

© Royal Society of Chemistry 2009. Received (in Cambridge, UK) 5th January 2009, Accepted 12th March 2009. First published on the web 23rd April 2009. We thank Chevron Energy Technology Company and Scripps Florida for financial support. Electronic supplementary information (ESI) available: Experimental details and DFT xyz coordinates. CCDC 697907–697909. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b823303a

Attached Files

Published - Young2009p4446Chem_Commun.pdf

Supplemental Material - Youngb823303a.pdf

Supplemental Material - Youngb823303a.txt

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Young2009p4446Chem_Commun.pdf

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Additional details

Identifiers

Eprint ID
15617
Resolver ID
CaltechAUTHORS:20090904-113907339

Funding

Chevron Energy Technology Co.
Scripps Florida

Dates

Created
2009-09-22
Created from EPrint's datestamp field
Updated
2021-11-08
Created from EPrint's last_modified field