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Published November 21, 2007 | Published + Accepted Version
Journal Article Open

Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis


Approaches to the preparation of enantioenriched materials via catalytic methods that destroy stereogenic elements of a molecule are discussed. Although these processes often decrease overall molecular complexity, there are several notable advantages including material recycling, enantiodivergence and convergence, and increased substrate scope. Examples are accompanied by discussion of the critical design elements required for the success of these methods.

Additional Information

© 2007 The Royal Society of Chemistry. Received 20 Jul 2007, Accepted 30 Aug 2007. First published online 01 Oct 2007. We thank NIH-NIGMS (R01 GM 080269-01), Eli Lilly (predoctoral fellowship to JTM), NDSEG (predoctoral fellowship to DCE), and NSF (predoctoral fellowship to DCE) for funding.

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Published - b711159m.pdf

Accepted Version - nihms243557.pdf


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