Published December 1, 1992
| Version Published
Journal Article
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Femtosecond vibrational transition-state dynamics in a chemical reaction
Creators
Abstract
We report the femtosecond dynamics of the vibrational motion in the transition-state evolution of an isomerization reaction. The observed nonstatistical and bound behavior reflects the localization in selective torsional and bending modes (of the 72 normal modes of the system). The multidimensionality of the potential energy surface is examined by comparing experiments with theoretical calculations.
Additional Information
© 1992 American Institute of Physics. Received 27 August 1992; accepted 30 September 1992. We wish to thank Professor J. Saltiel for helpful discussions and for providing us with the ultrapure sample. We also wish to acknowledge stimulating discussions with Professor W. Miller, Professor R. Marcus, and Professor D. Neumark. This work was supported by a grant from the US AFOSR and by the NSF. L. Bañares Fulbright/M.E.C. of Spain Postdoctoral Fellow. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 8712.Attached Files
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Additional details
Identifiers
- Eprint ID
- 3417
- Resolver ID
- CaltechAUTHORS:PEDjcp92
Funding
- Ministerio de Educación y Ciencia (MEC)
- Fulbright Foundation
- Air Force Office of Scientific Research (AFOSR)
- NSF
Dates
- Created
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2006-06-06Created from EPrint's datestamp field
- Updated
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2023-06-01Created from EPrint's last_modified field
Caltech Custom Metadata
- Other Numbering System Name
- Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 8712