Published September 21, 1977
| Published
Journal Article
Open
Initiation of Olefin Metathesis: Reaction of Deca-2,8-diene with Catalysts formed from Me_4Sn-WC1_6 and Me_3Al_2Cl_3-(Ph_3P)_2(NO)_2Cl_2Mo
- Creators
-
Grubbs, Robert H.
- Hoppin, Charles R.
Abstract
The initial product of the metathesis of deca-2,8-diene with metathesis catalysts formed from either Me_4Sn–WCl_6 or Me_3Al_2Cl_3–(Ph_3P)_2(NO)_2Cl_2Mo is propene; labelling of the terminal groups of the diene and the alkylating agents gives a labelling pattern in the propene that is best explained in terms of generation of a carbene in the initiation step from the alkylating agent.
Additional Information
© 1977 Royal Society of Chemistry. Received, 23rd June 1977; Com. 633.Attached Files
Published - GRUjcscc77a.pdf
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Additional details
- Eprint ID
- 32990
- Resolver ID
- CaltechAUTHORS:20120807-142624634
- Created
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2012-08-07Created from EPrint's datestamp field
- Updated
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2021-11-09Created from EPrint's last_modified field