Published May 22, 1999
| Published
Journal Article
Open
Direct observation of the femtosecond nonradiative dynamics of azulene in a molecular beam: The anomalous behavior in the isolated molecule
Abstract
Using femtosecond-resolved mass spectrometry in a molecular beam, we report real-time observation of the nonradiative, anomalous dynamics of azulene. We studied both S_2 and S_1 state dynamics. The motion of the wave packet in S_1 involves two time scales, a dephasing time of less than 100 fs and a 900±100 fs internal conversion. We discuss the dynamical picture in relation to the molecular structures and the conical intersection, and we compare with theory.
Additional Information
© 1999 American Institute of Physics. Received 27 January 1999; accepted 18 March 1999. This work was supported by the National Science Foundation and Office of Naval Research. S.D.F., a postdoctoral fellow of the Fund for Scientific Research-Flanders, acknowledges a Fulbright scholarship and financial support by the Katholieke Universiteit Leuven and by Caltech.Attached Files
Published - 1.478031.pdf
Files
1.478031.pdf
Files
(469.8 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:e2abd5ccfd839de6e7a184ebc92f5a0b
|
469.8 kB | Preview Download |
Additional details
- Eprint ID
- 69846
- Resolver ID
- CaltechAUTHORS:20160823-093537386
- NSF
- Office of Naval Research (ONR)
- Fonds Wetenschappelijk Onderzoek - Vlaanderen (FWO)
- Fulbright Foundation
- Katholieke Universiteit Leuven
- Caltech
- Created
-
2016-08-23Created from EPrint's datestamp field
- Updated
-
2021-11-11Created from EPrint's last_modified field