CaltechAUTHORS
Published April 6, 2011 | Version Supplemental Material
Journal Article Open

An Unusual Hydrogen Migration/C−H Activation Reaction with Group 3 Metals

Creators

  • 1. ROR icon University of California, Los Angeles
  • 2. ROR icon California Institute of Technology

Abstract

A novel hydrogen migration from the phenyl ring to the pyridine ring of an yttrium pyridyl complex supported by a 1,1′-ferrocene diamide ligand is reported. Density functional theory calculations were instrumental in probing the mechanism for this transformation.

Additional Information

© 2011 American Chemical Society. Received: November 22, 2010. Published: March 09, 2011. This work was supported by UCLA, the Sloan Foundation, and NSF (Grant CHE-0847735). Computational facilities were funded by grants from ARO-DURIP and ONR-DURIP. D.B., E.T., and W.A.G. acknowledge support from DOE (DE-PS36- 08GO98004P).

Attached Files

Supplemental Material - ja110505r_si_001.pdf

Supplemental Material - ja110505r_si_002.cif

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Additional details

Identifiers

Eprint ID
23555
DOI
10.1021/ja110505r
Resolver ID
CaltechAUTHORS:20110504-140724328

Related works

Describes
10.1021/ja110505r (DOI)

Funding

UCLA
Sloan Foundation
NSF
CHE-0847735
Army Research Office (ARO)-Defense University Research Instrumentation Program (DURIP)
Office of Naval Research (ONR)-Defense University Research Instrumentation Program (DURIP)
Department of Energy (DOE)
DE-PS36-08GO98004P

Dates

Created
2011-05-11
Created from EPrint's datestamp field
Updated
2021-11-09
Created from EPrint's last_modified field