Published September 15, 1953 | Version public
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Atomic theory of the lambda transition in helium

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Abstract

It is shown from first principles that, in spite of the large interatomic forces, liquid He4 should exhibit a transition analogous to the transition in an ideal Bose-Einstein gas. The exact partition function is written as an integral over trajectories, using the space-time approach to quantum mechanics. It is next argued that the motion of one atom through the others is not opposed by a potential barrier because the others may move out of the way. This just increases the effective inertia of the moving atom. This permits a simpler form to be written for the partition function. A rough analysis of this form shows the existence of a transition, but of the third order. It is possible that a more complete analysis would show that the transition implied by the simplified partition function is actually like the experimental one.

Additional Information

©1953 The American Physical Society. Received 15 May 1953. The author appreciates conversations with Edward Kerner and with M. Kac, as a result of which he became interested in the problem. He also is grateful for discussions with E. Wigner, H. Bethe, and R. F. Christy.

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2006-06-13
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