Published October 8, 1982
| public
Journal Article
Direct observation of intramolecular energy transfer by selective picosecond laser excitation of a single chromophore in jet-cooled molecules
Abstract
Here we report on the direct observation of time-resolved formation of a product of intramolecular energy transfer in isolated, jet-cooled A^*-CH_2-CH_2-CH_2-B. The anthracene chromophore (A) was excited by picosecond pulses, and the transfer of energy was probed at various excess energies by observing the emission arising from the exciplex formed between B (dimethyl aniline) and A^*. The threshold is at 3 kcal/mole.
Additional Information
© 1982 Elsevier B.V. Received 25 August 1982. This work was supported by the National Science Foundation under Grants number CHE-8112833 and number DMR-8105034. We are grateful to Professor D. Evans and his group for offering us their help and expertise in synthesizing DMA.Additional details
- Eprint ID
- 70545
- DOI
- 10.1016/0009-2614(82)83400-3
- Resolver ID
- CaltechAUTHORS:20160922-133203600
- NSF
- CHE-8112833
- NSF
- DMR-8105034
- Created
-
2016-09-30Created from EPrint's datestamp field
- Updated
-
2021-11-11Created from EPrint's last_modified field
- Other Numbering System Name
- Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 667